796034-71-4Relevant academic research and scientific papers
Nitrene transfer reactions catalyzed by gold complexes
Li, Zigang,Ding, Xiangyu,He, Chuan
, p. 5876 - 5880 (2006)
We report here the first gold-catalyzed nitrene transfer reaction. A gold(I) compound, supported by 4,4′,4″-tri-tert-butyl-2,2′: 6′,2″-terpyridine (tBu3tpy) as the ligand, efficiently catalyzes olefin aziridination with the use of the commercia
Photo-induced aziridination of alkenes with N-sulfonyliminoiodinanes
Masakado, Sota,Kobayashi, Yusuke,Takemoto, Yoshiji
, p. 688 - 690 (2018/06/11)
Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mech
Functionalization of Alkenes through Telescoped Continuous Flow Aziridination Processes
Hsueh, Nathanael,Clarkson, Guy J.,Shipman, Michael
supporting information, p. 4908 - 4911 (2016/10/18)
Alkenes can be efficiently aziridinated using highly soluble iminoiodane derivatives under continuous flow conditions. By combining the aziridine generation with nucleophilic ring opening reactions, a variety of products can be made without the need to ha
Copper-nitrenoid formation and transfer in catalytic olefin aziridination utilizing chelating 2-pyridylsulfonyl moieties
Han, Hoon,Seong, Byeong Park,Sang, Kyu Kim,Chang, Sukbok
, p. 2862 - 2870 (2008/09/20)
(Chemical Equation Presented) We have developed an efficient protocol for copper-catalyzed olefin aziridination using 5-methyl-2-pyridinesulfonamide or 2-pyridinesulfonyl azide as the nitrenoid source. The presence of a 2-pyridyl group significantly facil
Iron-catalysed aziridination reactions promoted by an ionic liquid
Mayer, Agathe C.,Salit, Anne-Frederique,Bolm, Carsten
supporting information; experimental part, p. 5975 - 5977 (2009/05/06)
A catalytic system based on iron(II) triflate, quinaldic acid and an ionic liquid allows the aziridination of olefins with equimolar amounts of iminoiodinane providing products in good to moderate yields. The Royal Society of Chemistry.
Iron-catalyzed aziridination reactions
Nakanishi, Masafumi,Salit, Anne-Frederique,Bolm, Carsten
scheme or table, p. 1835 - 1840 (2009/07/09)
A small quantity of iron(II) triflate (2.5 to 5 mol%) catalyzes the aziridination reactions of enol silyl ethers with tosylimino(iodo)benzene (PhINTs) in acetonitrile to give α-N-tosylamido ketones by subsequent aziridine ring opening. Olefins are convert
Notable coordination effects of 2-pyridinesulfonamides leading to efficient aziridination and selective aziridine ring opening
Han, Hoon,Bae, Imhyuck,Eun, Jeong Yoo,Lee, Junseong,Do, Youngkyu,Chang, Sukbok
, p. 4109 - 4112 (2007/10/03)
(Chemical Equation Presented) We have developed, on the basis of a chelation-strategy, an efficient copper-catalyzed aziridination protocol with the use of 5-methyl-2-pyridinesulfonamide and Phl(OAc)2. The reaction proceeds smoothly under mild conditions to give aziridines in moderate to good yields in the absence of external ligands or bases. The coordination-assisted approach offers the additional benefits that efficient deprotection of the N-substituent and selective aziridine ring-opening are effectively achieved.
