Chemistry Letters p. 1289 - 1292 (1981)
Update date:2022-08-05
Topics:
Nakai, Takeshi
Tanaka, Kiyoshi
Ogasawara, Kyo
Ishikawa, Nobuo
A novel synthetic method for 2,4-alkadienoic acids from allylic alcohols and 2,2,2-trifluoroethyl phenyl sulfoxide is described which involves the in situ Claisen rearrangement facilitated by the fluorine.This method was applied to the stereocontrolled synthesis of pellitorine, a natural insecticide.
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Doi:10.1016/S0008-6215(00)81868-6
(1981)Doi:10.1248/cpb.37.958
(1989)Doi:10.1021/ja00414a051
(1981)Doi:10.1080/00397911.2015.1071396
(2015)Doi:10.1016/S0022-328X(00)81924-5
(1981)Doi:10.1021/jm00344a015
(1982)
