79734-52-4

Upstream product

• 97590-64-2 (5R)-5-methyl-2-(hydroxymethylene)cyclohexanone 
• 917-54-4 methyllithium 
• 79767-65-0 cis R-(+)-2-ethylidene-5-methylcyclohexanone 
• 13368-65-5 (3R)-3-methylcyclohexanone 
• 75-07-0 acetaldehyde 
• 591-24-2 3-Methylcyclohexanone 
• 10458-14-7 Menthone 
• 89-82-7 pulegone 
• 86238-55-3 1-((R)-9-Methyl-1,4-dioxa-spiro[4.5]dec-6-yl)-ethanol 

Downstream Products

• 86238-56-4 (1R,5R)-2-Eth-(E)-ylidene-5-methyl-cyclohexanol 
• 79767-65-0 cis R-(+)-2-ethylidene-5-methylcyclohexanone 
• 86238-51-9 5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester 

Relevant academic research and scientific papers

NOVEL FLAVORING AGENTS COMPRISING 2-ALKYLIDENE-METHYLCYCLOHEXANONE BASED COMPOUNDS

PROBLEM TO BE SOLVED: To provide flavoring agents or flavoring agent compositions that impart a taste such as sweetness and a flavor with spicy and herb feelings, and have a more natural feeling. SOLUTION: The flavoring agent compounds are compounds repre

Chirality Transfer in Stereoselective Synthesis. A Highly Stereoselective Synthesis of Optically Active Vitamin E Side Chains

Employing the Carroll reaction as a means of chirality transfer, a highly efficient, stereochemically controlled, and generally applicable synthesis of optically active 1,5-dimethylated acyclic chains has been developed; as an example, the synthesis of the optically active C-15 vitamin E side chains 7a and 7b from (+)-pulegone in 12.6percent and 11.7percent overall yields, respectively, is described.

Conformational Studies of R-(+)-2-Alkylidene- and R-(-)-2-Benzylidene-5-methylcyclohexanones

The cis and trans 2-alkylidene-5-methylcyclohexanones have been separated and distinguished. 2-Benzylidene-5-methylcyclohexanone was also prepared in both forms.The CD, ORD, UV and IR spectra are recorded and discussed.The NMR data include solvent and tem

Thermolysis of alkylated 2-cyclohexenones and related monoterpenoid ketones

2-Cyclohexenone and three methylated cyclohexenones were thermolyzed at 400 deg C for 20 hours to give conversions to products in the range 11 to 45 percent.When three monoterpenes containing the cyclohexenone moiety were thermolyzed under the same conditions the conversions were over 75 percent.The major products formed were alkylated benzenes, alkylated phenols, and double bond isomers of the starting enones.Mechanisms are proposed to account for these products.