799247-45-3Relevant academic research and scientific papers
Asymmetric synthesis of the tetrahydropyran ring, C32-C38 fragment, of phorboxazoles
Brinkmann, Yasmin,Carreno, M. Carmen,Urbano, Antonio,Colobert, Francoise,Solladie, Guy
, p. 4335 - 4338 (2007/10/03)
(Chemical Equation Presented) The asymmetric synthesis of a model aldehyde (2R,6R)-2 and the C32-C38 fragment of phorboxazoles, (2R,4R,6R)-1, is described using a sulfoxide as chiral auxiliary. Key advances include the stereoselective reductions of β-keto
