802-51-7Relevant academic research and scientific papers
Synthesis and properties of iridium complexes based 1,3,4-oxadiazoles derivatives
Xu, Zhaowu,Li, Yang,Ma, Xuemei,Gao, Xindong,Tian, He
, p. 1860 - 1867 (2008/09/17)
A series of iridium complexes with 2,5-diaryl-[1,3,4]-oxadiazole ligands were synthesized and their electrochemical, photophysical, and electroluminescent (EL) properties studied. It was found that electron-withdrawing or donating substituents on the phenyl ring affected the emission maxima. Complex 3, iridium(III) bis(2,5-bis-(2-hydroxyphenyl)-[1,3,4]oxadiazolato-C2′,N3) (acetyl acetonate), was characterized by single-crystal X-ray structural determination. Three organic light emitting diodes devices were fabricated, which showed stable green-yellow luminescence.
Synthesis and properties of acene dimers linked by a 1,3,4-oxadiazole spacer
Ono, Katsuhiko,Wakida, Mayuko,Hosokawa, Ryohei,Saito, Katsuhiro,Nishida, Jun-ichi,Yamashita, Yoshiro
, p. 85 - 90 (2008/02/13)
Acene dimers linked by a 1,3,4-oxadiazole spacer were synthesized and their physical, optical, and electrochemical properties were investigated. The melting points and electron affinities of the dimers increased in the following order: benzene, naphthalene, and anthracene. The longest absorption maximum was red-shifted with an increase in the number of benzene rings. The conjugation between the two acene moieties through the oxadiazole spacer was not strong. Although no OFET properties were observed in a bottom contact device using the anthracene dimer as an active layer, the molecules were perpendicularly arranged on the substrate to form π-stacking films as observed in the X-Ray diffraction analysis.
Unusual Rearrangement in the Dehydration of Aroylated Butanodihydrazides
Tashtoush, Hasan,Al-Talib, Mahmoud,Odeh, Nedal
, p. 291 - 292 (2007/10/02)
Dehydration of N,N'-diaroylbutanodihydrazides 3a-f with phosphoryl chloride gave, unexpectedly, 2,5-diaryl-1,3,4-oxadiazoles 4a-f.However, dehydration of N,N'-dialkanoylbutanodihydrazides 1a-c afforded 5,5'-dialkyl-2,2'-(ethandiyl)-bis(1,3,4-oxadiazoles) 2a-c. Key Words: 1,3,4-Oxadiazole / Butanodihydrazides
