80204-19-9Relevant academic research and scientific papers
Formation of enehydrazine intermediates through coupling of phenylhydrazines with vinyl halides: Entry into the Fischer indole synthesis
Zhan, Fuxu,Liang, Guangxin
supporting information, p. 1266 - 1269 (2013/03/13)
Cut to the chase: Direct formation of an enehydrazine, an intermediate in the classic Fischer indole synthesis, solves the regioselectivity problem associated with indolization. This approach not only achieves selective synthesis of indoles through proper selection of the vinyl halide, but also leads to quick construction of desoxyeseroline and esermethole, as well as the key structural motif in the Akuammiline alkaloid vincorine. Copyright
A practical, stereoselective synthesis of (E)- and (Z)-2-bromo-2- pentenes
Kim, Heejin,Lee, Suk-Kwan,Lee, Dongreyoul,Cha, Jin Kun
, p. 729 - 735 (2007/10/03)
A short, stereoselective preparation of (E)-2-bromo-2-pentene and (Z)- 2-bromo-2-pentene is described starting from trans-2-methyl-2-pentenoic acid.
