80376-43-8Relevant academic research and scientific papers
New Synthetic Methods. Conjugate Addition of Alkyl Groups to Electron Deficient Olefins with Nitroalkanes as Alkyl Anion Equivalents
Ono, Noboru,Kamimura, Akio,Miyake, Hideyoshi,Hamamoto, Isami,Kaji, Aritsune
, p. 3692 - 3698 (2007/10/02)
The sequence of the Michael addition of nitroalkanes and denitration from the adduct provides a new and general method for conjugate addition of primary and secondary alkyl groups to electron deficient olefins such as α,β-unsaturated aldehydes, ketones, esters, nitriles, sulfoxides, and sulfones.
Sequential Ene Reactions. A New Annelation Procedure
Snider, Barry B.,Deutsch, Ethan A.
, p. 1822 - 1829 (2007/10/02)
Alkylidenecycloalkanes 1 undergo two sequential Me2AlCl-catalyzed ene reactions with α,β-unsaturated carbonyl compounds to give bicyclic alcohols 3.At low temperatures, the initial ene adducts 2 can be isolated when vinyl ketones are used.This reaction ha
Sequential Ene Reactions. A New Annelation Procedure
Snider, Barry B.,Deutsch, Ethan A.
, p. 745 - 747 (2007/10/02)
Alkylidenecycloalkanes react with α,β-unsaturated carbonyl compounds in the presence of Me2AlCl to give bicyclic alcohols resulting from two sequential ene reactions.
