97764-08-4Relevant academic research and scientific papers
Grignard reaction of substituted nitromethanes: The nwe observations
Gupta, Ramesh Chandra,Seth, M,Bhaduri, A P
, p. 745 - 747 (2007/10/02)
Reactions of 1-(1-nitromethyl)cyclohexene and its derivatives with excess of methylmagnesium iodide have been studied.In a few cases a chemoselective attack on the nitro group by the Grignard reagent has been observed.The N,N-dialkylhydroxylamine, the nor
New Synthetic Methods. Conjugate Addition of Alkyl Groups to Electron Deficient Olefins with Nitroalkanes as Alkyl Anion Equivalents
Ono, Noboru,Kamimura, Akio,Miyake, Hideyoshi,Hamamoto, Isami,Kaji, Aritsune
, p. 3692 - 3698 (2007/10/02)
The sequence of the Michael addition of nitroalkanes and denitration from the adduct provides a new and general method for conjugate addition of primary and secondary alkyl groups to electron deficient olefins such as α,β-unsaturated aldehydes, ketones, esters, nitriles, sulfoxides, and sulfones.
