804484-48-8Relevant academic research and scientific papers
Platinum(ii)-catalyzed selective: Para C-H alkoxylation of arylamines through a coordinating activation strategy
Shen, Jiabin,Xu, Jun,Cai, Heng,Shen, Chao,Zhang, Pengfei
, p. 490 - 497 (2019/01/24)
A highly efficient method to selectively install alkoxy onto the para position of arylamines via a coordinating activation strategy has been reported. Various substrates are compatible, providing the corresponding products in good to excellent yields. Thi
Solid-supported Pt-catalyzed remote C-H etherification of arylamines: A simple and practical approach for the synthesis of aromatic ethers
Han, Junfen,Wang, Guodong,Sun, Jian,Li, Hongshuang,Duan, Guiyun,Li, Furong,Xia, Chengcai
, (2019/06/18)
A simple and practical approach for a direct remote C-H etherification of arylamines with alcohol is developed herein by using a solid-supported Pt catalyst, hence providing a valuable method for the synthesis of aromatic ethers. The catalyst can easily b
Transition-metal free oxidative C-H etherification of acylanilines with alcohols through a radical pathway
Xu, Xiaobo,Chu, Zhengzhou,Xia, Chengcai
supporting information, p. 6346 - 6350 (2019/07/09)
A transition metal free approach for the synthesis of methyl/ethyl aryl ether via oxidative C-H etherification of acylanilines with alcohols has been developed. Various acylanilines are compatible under standard conditions, giving the corresponding produc
Green alternative solvents for the copper-catalysed arylation of phenols and amides
Sambiagio, Carlo,Munday, Rachel H.,John Blacker,Marsden, Stephen P.,McGowan, Patrick C.
, p. 70025 - 70032 (2016/08/06)
Investigation of the use of green organic solvents for the Cu-catalysed arylation of phenols and amides is reported. Alkyl acetates proved to be efficient solvents in the catalytic processes, and therefore excellent alternatives to the typical non-green solvents used for Cu-catalysed arylation reactions. Solvents such as isosorbide dimethyl ether (DMI) and diethyl carbonate also appear to be viable possibilities for the arylation of phenols. Finally, a novel copper catalysed acyl transfer process is reported.
Amide linkage isomerism as an activity switch for organometallic osmium and ruthenium anticancer complexes
Van Rijt, Sabine H.,Hebden, Andrew J.,Amaresekera, Thakshila,Deeth, Robert J.,Clarkson, Guy J.,Parsons, Simon,McGowan, Patrick C.,Sadler, Peter J.
supporting information; experimental part, p. 7753 - 7764 (2010/04/24)
We show that the binding mode adopted by picolinamide derivatives in organometallic OsII and RuII half-sandwich complexes can lead to contrasting cancer cell cytotoxicity. N-Phenyl picolinamide derivatives (XY) in OsII (1, 3-5, 7, 9) and RuII (2, 6, 8, 10
