804559-39-5

Basic information

• Product Name: (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98%
• Synonyms: (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98%;(R,R)-1,3-Bis(4-broMobenzyl)-2-chlorooctahydro-2-(2E)-crotyl-1H-1,3,2-benzodiazasilole;(3aR,7aR)-1,3-Bis[(4-bromophenyl)methyl]-2-(2E)-2-buten-1-yl-2-chlorooctahydro-1H-1,3,2-benzodiazasilole;(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(E)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole
• CAS NO: 804559-39-5
• Molecular Formula: C₂₄H₂₉Br₂ClN₂Si
• Molecular Weight: 568.84696
• Mol File: 804559-39-5.mol

Chemical Properties

• Melting Point: 92-96°C
• Boiling Point: 573.9±60.0 °C(Predicted)
• Appearance: white/solid
• Density: 1.46±0.1 g/cm3(Predicted)
• PKA: 6.35±0.20(Predicted)
• Sensitive: moisture sensitive
• CAS DataBase Reference: (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98%(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98%(804559-39-5)
• EPA Substance Registry System: (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98%(804559-39-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 804559-39-5(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
(1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98% is used as a reagent in organic synthesis for its ability to participate in various organic reactions, contributing to the formation of complex molecular structures.
Used in Silicon-based Materials Preparation:
In the field of materials science, (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98% is used as a precursor for the preparation of functionalized silicon-based materials, taking advantage of its unique structural features and reactivity.
Used in Advanced Chemical Research and Development:
Due to its high purity and specific stereochemistry, (1R,2R)-(-)-[N,N'-Bis(4-bromobenzyl)-1,2-cyclohexanediamino][(2E)-2-buten-1-yl]chlorosilane, min. 98% serves as an essential component in advanced chemical research and development, facilitating the discovery and innovation of new chemical processes and applications.

Upstream product

• 18147-55-2 (E)-crotyltrichlorosilane 
• 546084-44-0 (1R,2R)-N,N'-di(4'-bromobenzyl)-1,2-diaminocyclohexane 

Downstream Products

• 864498-78-2 benzyl 2-((2R,6S)-6-((2R,4R,5S)-2-(benzyloxy)-4-hydroxy-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate 
• 1357163-00-8 (1E,4R,5S)-1-(2-methoxy-phenyl)-5-methylhepta-1,6-dien-4-ol 
• 1357163-04-2 (1Z,4R,5S)-2-bromo-5-methyl-1-phenylhepta-1,6-dien-4-ol 
• 1357163-02-0 (1E,4R,5S)-5-methyl-1-(2-nitrophenyl)hepta-1,6-dien-4-ol 
• 1357162-95-8 (1E,4R,5S)-5-methyl-1-phenylhepta-1,6-dien-4-ol 
• 121155-51-9 (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol 
• 25201-44-9 (1S,2S)-2-methyl-1-phenyl-3-buten-1-ol 
• 25201-44-9 (1R,2R)-2-methyl-1-phenylbut-3-en-1-ol 
• 603994-07-6 (3R,4S)-1-(4'-methoxybenzyloxy)-4-methyl-5-hexen-3-ol 
• 79298-54-7 (-)-(2S,3S)-1-Benzyloxy-3-methyl-4-penten-2-ol 
• 83173-74-4 (3S,4R)-3-methyl-6-phenyl-1-hexen-4-ol 
• 89103-73-1 (3S,4S)-4-methyl-1-phenyl-5-hexen-3-ol 
• 129170-74-7 (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol? 
• 121842-20-4 (1E)-(3S,4R)-4-methyl-1-phenyl-1,5-hexadien-3-ol 

Relevant articles and documents

Highly diastereo- and enantioselective reagents for aldehyde crotylation

(Chemical Equation Presented) Two new, crystalline solid, storable, and highly enantioselective reagents for aldehyde crotylation have been developed. Both (cis and trans) crotylsilane reagents are easily prepared in bulk, require trivial reaction conditi