80522-43-6

Basic information

• Product Name: Silane, tris(1-methylethyl)(phenylmethoxy)-
• CAS NO: 80522-43-6
• Molecular Formula: C16H28OSi
• Molecular Weight: 264.483
• Mol File: 80522-43-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Silane, tris(1-methylethyl)(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, tris(1-methylethyl)(phenylmethoxy)-(80522-43-6)
• EPA Substance Registry System: Silane, tris(1-methylethyl)(phenylmethoxy)-(80522-43-6)

Safety Data

• Hazardous Substances Data: 80522-43-6(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 100-51-6 benzyl alcohol 
• 149063-93-4 triisopropylbromosilane 
• 13031-13-5 2-methoxy-2-phenylacetonitrile 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 100-52-7 benzaldehyde 
• 6485-79-6 chlorotriisopropylsilane 
• 114566-88-0 1-triisopropylsilanyl-1H-imidazole 

Downstream Products

• 100-51-6 benzyl alcohol 
• 1082056-30-1 bis(4-anisyl)methyl benzyl ether 
• 17877-23-5 triisopropylsilanol 
• 108-88-3 toluene 

Relevant articles and documents

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Breaking C-O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

We report herein the possibility to perform the hydrosilylation of carbonyls using actinide complexes as catalysts. While complexes of the uranyl ion [UO2]2+ have been poorly considered in catalysis, we show the potentialities of the Lewis acid [UO2(OTf)2] (1) in the catalytic hydrosilylation of a series of aldehydes. [UO2(OTf)2] proved to be a very active catalyst affording distinct reduction products depending on the nature of the reductant. With Et3SiH, a number of aliphatic and aromatic aldehydes are reduced into symmetric ethers, while iPr3SiH yielded silylated alcohols. Studies of the reaction mechanism led to the isolation of aldehyde/uranyl complexes, [UO2(OTf)2(4-Me2N-PhCHO)3], [UO2(μ-κ2-OTf)2(PhCHO)]n, and [UO2(μ-κ2-OTf)(κ1-OTf)(PhCHO)2]2, which have been fully characterized by NMR, IR, and single-crystal X-ray diffraction.

Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and is utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth-abundant transition-metal catalyst, mild reaction conditions, and the release of gases as the only byproducts (H 2 and CO 2).