80750-50-1Relevant articles and documents
DICHOTOMOUS REACTION PATHWAYS IN THE REACTION OF TRIARYLPHOSPHINE OXIDES WITH MEERWEIN'S SALT
Crich, David,Dyker, Hubert
, p. 475 - 476 (1989)
Addition of triphenylphosphine oxide to triethyloxonium tetrafluoroborate leads to the formation of ethoxytriphenylphosphonium tetrafluoroborate in high yield, whereas inverse addition leads an oxygen bridged diphosphonium salt.
A Stable Bromoalkoxyphosphorane, a Model for the Postulated Five-co-ordinate Intermediate in the Arbuzov and Related Reactions
Granoth, Itshak
, p. 735 - 740 (2007/10/02)
A stable model for the postulated intermediate in Arbuzov and related reactions, bromoalkoxyphosphorane (6), is obtained from the reaction of bromine and the phosphine ether (8).The analogous phosphine (13), however, gives benzyl bromide and the ionic alk