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PHOTOINDUCED N-β-HYDROXYALKYLATION OF TROPAN DERIVATIVES
Kostochka, L. M.,Skoldinov, A. P.,Lezina, V. P.
, p. 153 - 156 (2007/10/03)
The photooxidation of tropan derivatives by ketones was studied; the targeting of the reaction to the N-CH3 group with the formation of N-alkylation products and bis-tropan derivatives was demonstrated.The presence of two diastereomers in salts of N-alkyl derivatives of tropan was detected by PMR spectroscopy.An alternative method of synthesis of difficult-to-obtain amino alcohols was proposed.
