80924-06-7

Basic information

• Product Name: 1,3-O-(S)-Benzylidene-D-arabitol
• Synonyms: 1,3-O-(S)-Benzylidene-D-arabitol
• CAS NO: 80924-06-7
• Molecular Weight: 240.256
• Mol File: 80924-06-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-O-(S)-Benzylidene-D-arabitol (CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-O-(S)-Benzylidene-D-arabitol (80924-06-7)
• EPA Substance Registry System: 1,3-O-(S)-Benzylidene-D-arabitol (80924-06-7)

Safety Data

• Hazardous Substances Data: 80924-06-7(Hazardous Substances Data)

Upstream product

• 488-82-4 D-Arabitol 
• 100-52-7 benzaldehyde 

Downstream Products

• 164576-08-3 1,3-O-benzylidene-5-O-toluenesulfonyl-D-arabitol 
• 76696-06-5 (cyclic) 1,3'-Di-O-acetylbis(2,4-O-benzyliden-D-threose)-1,1':3,1'-Acetal 
• 652979-99-2 1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(dibenzylphosphate) 
• 652979-98-1 1,3-O-benzylidene-2-C-methyl-D-erythritol 4-dibenzylphosphate 
• 652980-00-2 1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(phosphoric acid monoester) 
• 652979-96-9 1,3-O-benzylidene-2-C-methyl-D-erythritol 4-(t-butyldimethylsilyl) ether 
• 652979-95-8 1,3-benzylidene-D-erythritol 4-(t-butyldimethylsilyl) ether 
• 652979-92-5 1,3-O-benzylidene-D-threitol 4-(t-butyldimethylsilyl) ether 
• 652979-94-7 1,3-O-benzylidene-D-erythrulose 4-(t-butyldimethylsilyl) ether 
• 652979-97-0 1,3-O-benzylidene-2-C-methyl-D-erythritol 
• 347362-36-1 1,3-benzylidene-D-erythritol 
• 81577-58-4 1,3-(R)-O-benzylidene-D-threitol 
• 745042-02-8 (2S,3S,4R)-1-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyloxy)-2-(tetracosanoylamino)nonane-3,4-diol 
• 745041-79-6 (2S,3S,4R)-3,4-O-isopropylidene-1-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2-tetracosanoylamino-1,3,4-nonanetriol 

Relevant articles and documents

First total synthesis of theopederin B

Total synthesis of theopederin B, isolated from marine sponge, was accomplished by coupling pederic acid, as the left half, with trioxodecaline amine as the right half. Key reactions for synthesizing the amine were SmI2-promoted Reformatsky rea

Synthesis of Enantiopure 2-C-Methyl-D-erythritol 4-Phosphate and 2,4-Cyclodiphosphate from D-Arabitol

(Equation presented) Two key intermediates of the newly discovered mevalonate-independent pathway for isoprenoid biosynthesis were prepared. Optically pure 2-C-methyl-D-erythritol 4-phosphate and 2,4-cyclodiphosphate were chemically synthesized from D-arabitol using a convenient benzylidene and tert-butyldimethylsilyl protection of polyhydroxylated intermediates. The new scheme offers a straightforward route to analogues and labeled forms.