81097-22-5

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-[[1-(2-propenyl)cyclohexyl]methyl]-
• CAS NO: 81097-22-5
• Molecular Formula: C17H25NO2S
• Molecular Weight: 307.457
• Mol File: 81097-22-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-[[1-(2-propenyl)cyclohexyl]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-[[1-(2-propenyl)cyclohexyl]methyl]-(81097-22-5)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-[[1-(2-propenyl)cyclohexyl]methyl]-(81097-22-5)

Safety Data

• Hazardous Substances Data: 81097-22-5(Hazardous Substances Data)

Upstream product

• 81097-43-0 1-allyl-1-(aminomethyl)cyclohexane 
• 98-59-9 p-toluenesulfonyl chloride 
• 676132-37-9 1-allylcyclohexane-1-nitrile 
• 766-05-2 cyclohexane carbonitrile 
• 67838-02-2 methyl 1-allylcyclohexane-1-carboxylate 
• 72335-83-2 1-allylcyclohexane-1-carboxylic acid chloride 
• 72335-77-4 1-Allyl-cyclohexanecarboxylic acid amide 
• 72335-50-3 1-(1-prop-2-enyl)cyclohexanecarboxylic acid 
• 4630-82-4 methyl cyclohexylcarboxylate 
• 67838-03-3 1-(1-(2-propenyl)cyclohexyl)methanol 
• 29517-58-6 1-allylcyclohexanecarbaldehyde 

Downstream Products

• 134786-21-3 N-tosyl-2-azaspiro<4,5>decane-3-methanol 
• 81097-23-6 N-tosyl-3-methyl-2-azaspiro<5,6>undec-3-ene 
• 1196712-31-8 4-fluoro-2-tosyl-2-azaspiro[5.5]undecane 
• 1322093-48-0 3-(bromomethyl)-2-tosyl-2-azaspiro[4.5]decane 

Relevant articles and documents

Gold(I)-catalyzed intra- and intermolecular hydroamination of unactivated olefins

Ph3PAuOTf catalyzes efficient intra- and intermolecular hydroamination of unactivated olefins with sulfonamides. Copyright

Photoredox-Catalyzed Intramolecular Aminodifluoromethylation of Unactivated Alkenes

A photoredox catalyzed aminodifluoromethylation of unactivated alkenes has been developed in which HCF2SO2Cl is used as the HCF2 radical source. Sulfonamides were active nucleophiles in the final step of a tandem addition/oxidation/cyclization process to form pyrrolidines, and esters were found to cyclize to form lactones. Thus, a variety of pyrrolidines and lactones were obtained in moderate to excellent yield. In order for the cyclization reactions to be efficient, a combination of a copper catalyst (Cu(dap)2Cl) and silver carbonate was crucial to suppressing a competing chloro, difluoroalkylation process.

Regioselective copper(II)-mediated bromoamination of unfunctionalized olefins: An efficient route to N-heterocyclic compounds

Bromoamination of unfunctionalized olefins was realized under mild conditions using copper(II) bromide (CuBr2) as both reaction promoter and bromine source. The reactions could be carried out under open air at ambient temperature, and both N-alkylated and N-tosylated substrates could be converted to the corresponding N-heterocyclic compounds in high regioselectivity and good isolated yields. A variety of biologically important structures could be obtained via subsequent nucleophilic substitution reactions.