72335-83-2Relevant academic research and scientific papers
mCPBA-mediated dioxygenation of unactivated alkenes for the synthesis of 5-imino-2-tetrahydrofuranyl methanol derivatives
Deng, Xiaojun,Zhang, Luwen,Liu, Huixia,Bai, Yu,He, Wei
, (2020/11/24)
A mCPBA-mediated, metal-free, intramolecular dioxygenation reaction of unactivated alkenes is reported. In the presence of m-chlorobenzoic peracid, different unsaturated amide substrates could be cyclized via epoxide intermediates, producing the corresponding 5-imino-2-tetrahydrofuranyl methanol products in up to 94% yield at room temperature.
Palladium-catalyzed carbonylation of homoallylic amine derivatives in the presence of a copper co-catalyst
Mizutani, Takanori,Ukaji, Yutaka,Inomata, Katsuhiko
, p. 1251 - 1256 (2007/10/03)
γ-Lactams were synthesized from N-tosylhomoallylamines by a carbonylation reaction catalyzed by palladium and copper salts under the normal pressure of CO and O2 at room temperature. Monocarbonylation proceeded by the use of [PdCl2(C
CYCLISATION DE N-TOSYL OXIRANES-PROPYLAMINES: SYNTHESE D'HETEROCYCLES AZOTES.
Nuhrich, A.,Moulines, J.
, p. 3075 - 3088 (2007/10/02)
The cyclisation of N-tosyl-oxiranepropylamines is accomplished in aqueous basic medium and in anhydrous acid medium as well.In most cases, this reaction occurs by a regiospecific 5-exo-tet. ring closure and affords N-tosyl-2-pyrrolidinemethanols in high y
An Efficient and General Synthesis of 5-Substituted Pyrrolidinones
Miller, R. D.,Goelitz, P.
, p. 1616 - 1618 (2007/10/02)
2-Pyrrolidinone derivatives are widespread materials of considerable laboratory and commercial importance.In spite of this, there is no generally useful synthesis of either symmetrically or unsymmetrically 5,5-disubstituted derivatives.This is particularl
