81408-40-4

Upstream product

• 81408-32-4 5-O-benzyl-1,2:3,4-di-O-isopropylidene-D-rhamnitol 
• 100-44-7 benzyl chloride 
• 53346-05-7 2-(benzyloxy)propanal 
• 3761-92-0 n-hexylmagnesium bromide 
• 81408-33-5 5-O-benzyl-D-rhamnitol 

Downstream Products

• 81408-34-6 (2S,3R)-2-O-benzyl-2,3-nonanediol 
• 81408-36-8 (2S,3S)-2-O-benzyl-2,3-nonanediol 
• 81408-35-7 Methanesulfonic acid (R)-1-((S)-1-benzyloxy-ethyl)-heptyl ester 
• 81408-37-9 (2S,3S)-2-O-benzyl-3-O-methanesulfonyl-2,3-nonanediol 
• 81408-44-8 (2S,3R)-3-(adenin-9-yl)-2-O-benzyl-2-nonanol 
• 81408-42-6 (2S,3S)-3-(adenin-9-yl)-2-O-benzyl-2-nonanol 
• 81408-48-2 (2R,3S)-3-(adenin-9-yl)-2-O-benzyl-2-nonanol 
• 81408-49-3 (2R,3S)-3-(adenin-9-yl)-2-nonanol hydrochloride 
• 81408-41-5 Methanesulfonic acid (R)-1-((R)-1-benzyloxy-ethyl)-heptyl ester 
• 81408-50-6 (2S)-2-(benzyloxy)-3-nonanone 

Relevant academic research and scientific papers

ZnBr2-MEDIATED HIGHLY DIASTEREOSELECTIVE ADDITION OF GRIGNARD REAGENTS TO α-BENZYLOXY ALDEHYDES

α-Benzyloxy aldehydes reacted with Grignard reagents in the presence of ZnBr2 to afford vicinal syn-diol derivatives with high diastereoselectivity.

Synthesis of Inhibitors of Adenosine Deaminase. A Total Synthesis of erythro-3-(Adenin-9-yl)-2-nonanol and Its Isomers from Chiral Precursors

The synthesis of both isomers of EHNA2 ("erythrohydroxynonyladenine") from D- and L-rhamnose is described.The key intermediates, (R)- and (S)-2-(benzyloxy)propanal, derived respectively from 5-O-benzyl-D- and -L-rhamnitol, were each condensed w