81417-97-2

Basic information

• Product Name: Cyclohexanemethanol, a-3-butenyl-
• CAS NO: 81417-97-2
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• Mol File: 81417-97-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanemethanol, a-3-butenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, a-3-butenyl-(81417-97-2)
• EPA Substance Registry System: Cyclohexanemethanol, a-3-butenyl-(81417-97-2)

Safety Data

• Hazardous Substances Data: 81417-97-2(Hazardous Substances Data)

Upstream product

• 7051-34-5 cyclopropylcarbinyl bromide 
• 2043-61-0 cyclohexanecarbaldehyde 
• 1344115-80-5 CH₂CH₂CHCH₂BO₂(CH₂)3 
• 5162-44-7 1-bromo-4-butene 
• 2100-17-6 4-pentenal 
• 931-50-0 cyclohexylmagnesium bromide 
• 626-62-0 Cyclohexyl iodide 
• 7103-09-5 4-but-1-enylmagnesium bromide 

Downstream Products

• 1206670-38-3 C₂₃H₃₅NO₄S 
• 1010081-72-7 (E)-6-cyclohexyl-6-hydroxyhex-2-enal 
• 200641-13-0 (E)-1-Cyclohexyl-5-(toluene-4-sulfonyl)-pent-4-en-1-ol 
• 101567-04-8 (RS)-5-cyclohexyl-3-methylenedihydrofuran-2(3H)-one 
• 727665-03-4 1-cyclohexylpent-4-enyl acetate 
• 727665-55-6 (1-azidopent-4-enyl)cyclohexane 
• 190730-19-9 1-Cyclohexyl-4-iodo-5-(toluene-4-sulfonyl)-pentan-1-ol 

Relevant articles and documents

Organocatalytic synthesis of polysubstituted tetrahydrofurans from alkenes

A novel, organocatalytic and environmentally friendly protocol for the synthesis of polysubstituted tetrahydrofurans from trivial starting materials has been described. By employing 2,2,2-trifluoroacetophenone-mediated oxidation, which utilizes H2O2 as a green oxidant, we introduce a sustainable procedure that embraces the principles of green chemistry for the production of substituted tetrahydrofurans in high to excellent yields and tolerates a wide range of substitution patterns.

Indium-copper and indium-silver mediated Barbier-Grignard-type alkylation reaction of aldehydes using unactivated alkyl halides in water

(Chemical Equation Presented) An efficient method has been developed for the Barbier-Grignard-type alkylation reaction of aldehydes (including aliphatic version) using unactivated alkyl halides in water in the presence of an In/CuI/I2 or In/AgI/I2 system. The reactions proceeded more efficiently in water than in organic solvent. In, CuI or AgI, and I 2 were all essential for the efficient progress of the reactions. A radical-type reaction mechanism was studied and proposed by using 4-pentenal as substrate.

A facile method for synthesis of 5-hydroxypentene via sonochemical barbier reaction

A series of 5-hydroxypentenes was synthesized from the reaction mixture of Mg powder, 1,2-dibromoethane, 4-bromobutene and aldehydes in THF under ultrasound. This sonochemical Barbier reaction provides a simple and alternative method for preparation of 5-hydroxypentene instead of the allylating reagent with epoxide.