81470-83-9

Upstream product

• 116661-41-7 (2S,4R,5R)-1-(benzyloxy)-5-hydroxy-2,4,6-trimethylhept-6-en-3-one 
• 73814-75-2 [(2S,3S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 81470-80-6 {(2S,3S)-3-[(R)-1-((4S,5R)-2,2,5-Trimethyl-[1,3]dioxan-4-yl)-ethyl]-oxiranyl}-methanol 
• 81470-78-2 (E)-(S)-4-((4R,5R)-2,2,5-Trimethyl-[1,3]dioxan-4-yl)-pent-2-enoic acid ethyl ester 
• 81470-79-3 (E)-(S)-4-((4R,5R)-2,2,5-Trimethyl-[1,3]dioxan-4-yl)-pent-2-en-1-ol 
• 81470-81-7 (2R,3R,4S)-2-Methyl-4-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-pentane-1,3-diol 
• 81470-73-7 ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate 
• 96554-52-8 (-)-(2R,3S,4R)-3,5-dihydroxy-2,4-dimethylpentanal 3,5-acetonide 
• 102849-23-0 (+)-(2R,3S,4S)-1,3,5-trihydroxy-2,4-dimethylpentane 3,5-acetonide 
• 81470-77-1 (2S,3R,4R)-1-(benzyloxy)-3,5-(isopropylidenedioxy)-2,4-dimethylpentane 
• 108393-30-2 (2R,3R,4R)-5-(benzyloxy)-2,4-dimethyl-1,3-pentanediol 
• 81520-03-8 (2E,4R)-5-(benzyloxy)-4-methyl-2-penten-1-ol 
• 81470-82-8 (2R,3R,4S)-1-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-4-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-pentan-3-ol 

Downstream Products

• 81470-84-0 2,2-Dimethyl-propionic acid (2R,3R,4R,5R,6R)-7-(tert-butyl-diphenyl-silanyloxy)-3,5-dihydroxy-2,4,6-trimethyl-heptyl ester 
• 81470-85-1 (R)-2-{(4S,5R,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-propan-1-ol 
• 81470-88-4 (E)-(R)-4-{(4S,5R,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-pent-2-en-1-ol 
• 81470-90-8 (2S,3S,4R)-4-{(4S,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-2-methyl-pentane-1,3-diol 
• 82992-42-5 (2R,3S,4S)-2-{(4S,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-4-methyl-hex-5-en-3-ol 
• 81470-91-9 tert-Butyl-diphenyl-((R)-2-{(4S,5S,6S)-2,2,5-trimethyl-6-[(R)-1-((4R,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-propoxy)-silane 
• 81479-08-5 2,2-Dimethyl-propionic acid (R)-2-{(4S,5R,6S)-6-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-propyl ester 
• 81470-87-3 (E)-(R)-4-{(4S,5R,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-pent-2-enoic acid ethyl ester 
• 81470-86-2 (S)-2-{(4R,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-propionaldehyde 
• 81470-89-5 [(2S,3S)-3-((S)-1-{(4R,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-ethyl)-oxiranyl]-methanol 
• 81470-89-5 [(2R,3R)-3-((S)-1-{(4R,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-ethyl)-oxiranyl]-methanol 

Relevant academic research and scientific papers

Studies in Polypropionate Synthesis: A General Approach to the Synthesis of Stereopentads.

A general protocol for the synthesis of specific isomers of the stereopentad 1 from the α-chiral ethyl ketones (R)- and (S)-2 has been developed.From (S)-2, this involves stepwise elaboration of each of the three aldol adducts 3, 4 and 5 by stereoselectiv