81549-23-7

Basic information

• Product Name: 3,4-dihydro-3-hydroxy-3-phenyl-2H-1-benzothiopyran
• Synonyms: 3,4-dihydro-3-hydroxy-3-phenyl-2H-1-benzothiopyran
• CAS NO: 81549-23-7
• Molecular Weight: 242.342
• Mol File: 81549-23-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,4-dihydro-3-hydroxy-3-phenyl-2H-1-benzothiopyran(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-dihydro-3-hydroxy-3-phenyl-2H-1-benzothiopyran(81549-23-7)
• EPA Substance Registry System: 3,4-dihydro-3-hydroxy-3-phenyl-2H-1-benzothiopyran(81549-23-7)

Safety Data

• Hazardous Substances Data: 81549-23-7(Hazardous Substances Data)

Upstream product

• 81549-15-7 3-acetoxy-2H-1-benzothiopyran 
• 39161-85-8 alpha-mercaptophenylacetic acid 
• 65927-22-2 2-<(carboxymethyl)thio>benzeneacetic acid 
• 14092-00-3 methyl o-tolyl sulfide 
• 98-88-4 benzoyl chloride 
• 16895-58-2 2H-1-benzothiopyran-3(4H)-one 

Downstream Products

• 53844-17-0 3-phenyl-2H-1-benzoyhiopyran 
• 5814-85-7 1,2-diphenylpropane 
• 81549-24-8 2-phenyl-2H-1-benzothiopyran-S,S-dioxide 

Relevant articles and documents

Metalation reactions XIII. The reactions of electrophiles with the dilithiated species 1-(α-lithiomethyl)-2-benzene

Direct dimetalation of 1-methyl-2-(methylthio)benzene (1) gives the dilithiated species (2) in good yield, which can be used to introduce substituents into the thiomethyl and methyl groups.Species 2 can react also with a variety of dichlorosilanes and dichlorostannanes, and with sulphur chloride, to yield derivatives of 1,3-benzothiasilin, 1,3-benzothiastannin and 1,3-benzodithiin respectively.Reaction of 2 with tetrachlorosilane yields a spirocyclic silicon compound, while reaction with benzoyl chloride yields a derivative of 1-benzothiopyran.