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5-Thiazolecarboxylic acid, 2-bromo-4-methyl-, 1,1-dimethylethyl ester (9CI) is a chemical compound with the molecular formula C8H12BrNO2S. It is an ester derivative of 5-thiazolecarboxylic acid, featuring a 2-bromo-4-methyl-thiazole ring and a tert-butyl ester group. 5-Thiazolecarboxylicacid,2-bromo-4-methyl-,1,1-dimethylethylester(9CI) is characterized by its potential applications in the synthesis of various pharmaceuticals and agrochemicals, as well as its role as an intermediate in organic chemistry. The presence of the bromine atom and the methyl group on the thiazole ring, along with the tert-butyl ester, contribute to its unique chemical properties and reactivity.

81569-41-7

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81569-41-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 81569-41-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,1,5,6 and 9 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 81569-41:
(7*8)+(6*1)+(5*5)+(4*6)+(3*9)+(2*4)+(1*1)=147
147 % 10 = 7
So 81569-41-7 is a valid CAS Registry Number.

81569-41-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl 2-bromo-4-methylthiazole-5-carboxylate

1.2 Other means of identification

Product number -
Other names 2-Bromo-4-methyl-thiazole-5-carboxylic acid tert-butyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:81569-41-7 SDS

81569-41-7Downstream Products

81569-41-7Relevant academic research and scientific papers

METHODS OF TREATMENT WITH AMINOLEVULINIC ACID SYNTHASE 2 (ALAS2) MODULATORS

-

, (2020/12/29)

Described herein is a compound of Formula I or a pharmaceutically acceptable salt thereof: wherein Ring A R1, R2, a, b, and n are as defined herein. Also described is a method of treating a subject having a disorder in need of treatment, comprising inhibiting aminolevulinic acid synthase 2 (ALAS2) in the subject by administering a compound of Formula (I) or a pharmaceutically acceptable salt thereof. Disorders that are of particular interest are blood disorders, such as porphyria and anemia.

In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides

Milner, Phillip J.,Yang, Yang,Buchwald, Stephen L.

supporting information, p. 4775 - 4780 (2015/10/28)

A thorough investigation of the challenging Pd-catalyzed fluorination of five-membered heteroaryl bromides is presented. Crystallographic studies and density functional theory (DFT) calculations suggest that the challenging step of this transformation is

The Preparation of Thiazole-4- and -5-carboxylates, and an Infrared Study of their Rotational Isomers

Barton, Anne,Breukelman, Stephen P.,Kaye, Perry T.,Meakins, G. Denis,Morgan, David J.

, p. 159 - 164 (2007/10/02)

Convenient general procedures have been developed for preparing series of thiazole-4- and -5-carboxylates containing alkyl and halogeno substituents.While both series of esters show i.r. carbonyl doublets caused by rotational isomerism, the more intense absorptions of the 4-carboxylates are the lower wavenumber components, whereas those of the 5-carboxylates are the higher wavenumber components.In both series the stronger bands arise from the thermochemically more stable forms; identification of these forms as the carbonyl O,S-syn-s-trans rotamers is more certain with the 4-carboxylates than with the 5-carboxylates.

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