81616-11-7

Basic information

• Product Name: Carbonic acid, 1-methoxyethenyl phenylmethyl ester
• CAS NO: 81616-11-7
• Molecular Formula: C11H12O4
• Molecular Weight: 208.214
• Mol File: 81616-11-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbonic acid, 1-methoxyethenyl phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, 1-methoxyethenyl phenylmethyl ester(81616-11-7)
• EPA Substance Registry System: Carbonic acid, 1-methoxyethenyl phenylmethyl ester(81616-11-7)

Safety Data

• Hazardous Substances Data: 81616-11-7(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 3600-21-3 mercury(II) bis-methylacetate 
• 100-51-6 benzyl alcohol 

Downstream Products

• 1148-11-4 N-Benzyloxycarbonyl-L-proline 
• 39896-97-4 benzyl-carbamic acid benzyl ester 
• 81616-15-1 N-benzyl-N-methylcarbamic acid benzyl ester 
• 1161-13-3 N-Cbz-L-Phe 
• 1142-20-7 N-Cbz-Ala 
• 1138-80-3 N-(Benzyloxycarbonyl)glycine 

Relevant articles and documents

Amino-Protecting Reagents: New Promising Reagents for tert-Butoxycarbonylation, Benzyloxycarbonylation, and carbonylation

A new method for the preparation of tert-butyl- (1d), benzyl- (1e), and (β-trimethylsilyl)ethyl α-methoxyvinyl carbonates (1f) has been devised.The reaction of these reagents with amino compounds proceeds rapidly under mild conditions to give the corresponding N-tert-butoxycarbonylated (N-Boc), N-benzyloxycarbonylated (N-Z), and N-carbonylated (N-Tmseoc) compounds in quantitative yields.Twenty-two examples using amines, amino alcohols, and amino acids were presented.