81807-67-2Relevant academic research and scientific papers
Formation of trisubstituted buta-1,3-dienes and α,β-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents
Dvo?áková, Hana,Koudelka, Jakub,Oeser, Petr,Tobrman, Tomá?
, p. 35109 - 35120 (2020/10/19)
We studied the reactions of vinyl phosphates and vinyl phosphordiamidates containing an ester functional group with organometallic reagents. We found that the functionalized vinyl phosphates were smoothly converted into tri- and tetrasubstituted buta-1,3-
Polarized Ketene Dithioacetals. Part 42. Studies on the Reactions of Alkyl and Aryl Grignard Reagents with α-Oxoketene Dithioacetals
Singh, Gurdeep,Purkayastha, Makhan L.,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 1289 - 1294 (2007/10/02)
The oxoketene dithioacetals (2a-k) derived from a variety of cyclic and acyclic active methylene ketones undergo 1,2-addition with methylmagnesium iodide to give the alcohol acetals (3a-k) which, on subsequent boron trifluoride-ether catalysed methanolysi
