81903-08-4Relevant articles and documents
SYNTHESIS OF SULFONATED 1,2-DICYANOBENZENES
Negrimovsky, V. M.,Derkacheva, V. M.,Luk'yanets, E. A.,Weitemeyer, A.,Woehrle, D.,Schneider, G.
, p. 161 - 168 (2007/10/03)
Employing the corresponding halogen or amino (via the diazonium salts) substituted 1,2-dicyanobenzenes as starting materials 2,3- and 3,4-dicyanobenzenesulfonic acids (3) and (4) are synthesized.Several intermediates useful for the preparation of the sulfonic acids (3) and (4) are also obtained: 3- and 4-mercapto-1,2-dicyanobenzenes (5), (16), 2,3- and 3,4-dicyanobenzenesulfonyl chlorides (10), (11), bis(2,3-dicyanophenyl)- and bis(3,4-dicyanophenyl)-disulfides (14), (15), and several sulfonamides (17)-(24) (from the sulfochlorides (10), (11).In addition, the synthesis of 4-(4-phonoxy-1,2-dicarbonitrile)benzenesulfonic acid (26) is described. Key words: Dicyanobenzenesulfonic acids, 1,2-dicyanobenzene substituted, phthalonitrile substituted.