82053-22-3

Upstream product

• 141320-38-9 (2S,3S)-2-Bromo-3-methoxy-2-methyl-3-phenyl-propionic acid methyl ester 
• 189089-27-8 methyl 3-methoxy-3-phenyl-2-methylene-propanoate 
• 67-56-1 methanol 
• 82053-24-5 erythro-3-methoxy-2-methyl-3-phenylpropanoic acid t-butylthio ester 
• 1039757-85-1 (S)-N-[(2R,3S)-3-methoxy-2-methyl-3-phenylpropanoyl]-4-phenyl-1,3-thiazolidine-2-thione 
• 1039757-87-3 (S)-4-benzyl-N-[(2R,3S)-3-methoxy-2-methyl-3-phenylpropanoyl]-1,3-thiazolidine-2-thione 
• 137720-28-6 (2R,3R)-2-Iodo-3-methoxy-2-methyl-3-phenyl-propionic acid methyl ester 
• 137720-28-6 (2S,3R)-2-Iodo-3-methoxy-2-methyl-3-phenyl-propionic acid methyl ester 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 22946-43-6 (E)-methyl-2-methyl-3-phenylacrylate 
• 100-52-7 benzaldehyde 
• 18020-59-2 methyl 3-hydroxy-2-methylidene-3-phenylpropionate 
• 72658-03-8 (Z)-1-methoxy-1-(trimethylsiloxy)propene 
• 72658-09-4 (E)-(1-methoxyprop-1-enyloxy)trimethylsilane 

Relevant academic research and scientific papers

On the influence of chiral auxiliaries in the stereoselective cross-coupling reactions of titanium enolates and acetals

Titanium enolates from chiral N-propanoyl-1,3-thiazolidine-2-thiones containing bulky substituents at C4 turned out to be excellent platforms to get highly stereocontrolled cross-coupling reactions with acetals. Related oxazolidinethiones also afforded go

Magnesium Bromide Mediated Highly Diastereoselective Heterogeneous Hydrogenation of Olefins

(Matrix Presented) Palladium on carbon combined with magnesium bromide catalyzed hydrogenation of Baylis-Hillman olefins to afford the corresponding aldol derivatives in a highly syn-diastereoselective manner is described.

The Use of Lewis Acids in Radical Chemistry. Chelation-Controlled Radical Reductions of Substituted α-Bromo-β-alkoxy Esters and Chelation-Controlled Radical Addition Reactions

The radical reduction of a series of α-bromo-β-alkoxy esters under chelation-controlled conditions is reported. Proceeding with high stereoselectivity in the presence of MgBr2middot;OEt2, reductions give access to syn products. Syste

TRIMETHYLSILYL TRIFLATE CATALYZED ALDOL-TYPE REACTION OF ENOL SILYL ETHERS AND ACETALS OR RELATED COMPOUNDS

Trimethylsilyl triflate with or without added hindered tertiary amines catalyzes directed condensation of enol trimethylsilyl ethers with acetals, orthoformate, or 2-acetoxytetrahydrofuran or -pyrans to give the corresponding β-alkoxy carbonyl compounds.R

TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS

Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.