82228-11-3

Upstream product

• 186697-04-1 benzyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 34246-23-6 benzyl D-glucopyranoside 
• 50-99-7 D-glucose 
• 100-51-6 benzyl alcohol 
• 79549-73-8 benzyl 4,6-O-(phenylmethylene)-α-D-glucopyranoside 
• 58650-53-6 benzyl endo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 82228-12-4 benzyl 2,4-di-O-benzyl-α-D-glucopyranoside 
• 53929-39-8 benzyl 3-O-allyl-2-O-benzyl-4,6-benzylidene-α-D-mannopyranoside 
• 69401-46-3 benzyl 2,4-di-O-benzyl-α-D-mannopyranoside 
• 86342-14-5 benzyl 3-O-allyl-2,4-di-O-benzyl-6-O-(p-toluenesulfonyl)-α-D-mannopyranoside 
• 86342-18-9 benzyl 2,4-di-O-benzyl-α-D-rhamnopyranoside 
• 86342-16-7 benzyl 3-O-allyl-2,4-di-O-benzyl-α-D-rhamnopyranoside 
• 58527-92-7 benzyl 3-O-allyl-2,4-di-O-benzyl-α-D-mannopyranoside 
• 82186-23-0 benzyl 2,4-di-O-benzyl-3,6-di-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 82186-26-3 benzyl 2,4-di-O-benzyl-6-O-β-D-glucopyranosyl-3-O-(3-O-β-D-glucopyranosyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 82186-20-7 benzyl 6-O-acetyl-2,4-di-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 82186-22-9 benzyl 2,4-di-O-benzyl-6-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 82186-24-1 benzyl 2,4-di-O-benzyl-3,6-di-O-β-D-glucopyranosyl-α-D-glucopyranoside 
• 82186-19-4 benzyl 6-O-acetyl-2,4-di-O-benzyl-α-D-glucopyranoside 
• 82186-25-2 benzyl 2,4-di-O-benzyl-6-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-3-O-<2,4,6-tri-O-acetyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-β-D-glucopyranosyl>-α-D-glucopyranoside 

Relevant academic research and scientific papers

Total Synthesis of a Hyperbranched N-Linked Hexasaccharide Attached to ATCV-1 Major Capsid Protein without Precedent

The N-glycans attached to some chloroviruses comprise a hyperbranched core structure without precedent. We are interested in the chemical synthesis of the hexasaccharide attached to ATCV-1 (Acanthocystis turfacea Chlorella virus 1) for its distinct structure. After exploring four routes, the target hexasaccharide 2 was successfully synthesized for the first time in overall 10% yield over 8 steps from thioglycoside building blocks. This synthetic protocol is characterized by the three-component one-pot glycosylation and the regioselective glycosylation reactions. The disclosed synthetic approach to this new type of N-glycans will facilitate the in-depth understanding of their biological functions.

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga

SYNTHESIS OF A BRANCHED D-GLUCOTETRAOSE, THE REPEATING UNIT OF THE EXTRACELLULAR POLYSACCHARIDES OF Grifola umbellate, Sclerotinia libertiana, Porodisculus pendulus, AND Schizophyllum commune FRIES

The synthesis of D-glucotetraose, 3-O--6-O-β-D-glucopyranosyl-α (and β)-D-glucopyranose, the repeating unit of the extracellular polysaccharides of Grifora umbellata, Sclerotinia libertiana, Porodisculus pendulus, and Schizophyllum commune Fries, is described.