82264-32-2

Basic information

• Product Name: methyl β-D-glucopyranoside 6-benzyl ether
• Synonyms: methyl β-D-glucopyranoside 6-benzyl ether
• CAS NO: 82264-32-2
• Molecular Weight: 284.309
• Mol File: 82264-32-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: methyl β-D-glucopyranoside 6-benzyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: methyl β-D-glucopyranoside 6-benzyl ether(82264-32-2)
• EPA Substance Registry System: methyl β-D-glucopyranoside 6-benzyl ether(82264-32-2)

Safety Data

• Hazardous Substances Data: 82264-32-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 709-50-2 methyl beta-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 2641-79-4 methyl 2,3,4,6-tetrakis-O-trimethylsilyl-α-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 6748-91-0 methyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 67-56-1 methanol 
• 115850-12-9 p-nitrophenyl 6⁵-O-benzyl-α-maltopentaoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 492-62-6 alpha-D-glucopyranose 
• 162284-50-6 methyl 2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 245047-78-3 methyl 6-O-benzyl-2-O-(8-sulfanyl-3,6-dioxaoctyl)-α-D-glucopyranoside 
• 245047-75-0 Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-2-benzyloxymethyl-5-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-6-methoxy-tetrahydro-pyran-3-yl ester 
• 245047-77-2 methyl 6-O-benzyl-2-O-(8-p-tolylsulfonyl-3,6-dioxaoctyl)-α-D-glucopyranoside 
• 245047-80-7 methyl 6-O-benzyl-2-O-(11,14-dioxo-3,6-dioxa-9-thiapentadecyl)-α-D-glucopyranoside 
• 245047-73-8 methyl 3,4-di-O-acetyl-6-O-benzyl-2-O-[8-(tert-butyldimethylsilyloxy)-3,6-dioxaoctyl]-α-D-glucopyranoside 
• 245047-76-1 Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-2-benzyloxymethyl-6-methoxy-5-(2-{2-[2-(toluene-4-sulfonyloxy)-ethoxy]-ethoxy}-ethoxy)-tetrahydro-pyran-3-yl ester 
• 1613160-51-2 methyl 6-O-benzyl-3,4-O-isopropylidene-α-D-glucopyranoside 
• 1613160-52-3 methyl 6-O-benzyl-2,3-O-isopropylidene-α-D-glucopyranoside 
• 1613160-55-6 methyl 6-O-benzyl-2,3-O-isopropylidene-α-D-allopyranoside 
• 1613160-54-5 methyl 6-O-benzyl-2,3-O-isopropylidene-α-D-allopyranoside 
• 1613160-53-4 methyl 6-O-benzyl-2,3-O-isopropylidene-α-D-allo-hexopyranosid-4-ulose 
• 863554-23-8 methyl 6-O-benzyl-3,4-O-isopropylidene-α-D-allopyranoside 
• 863554-17-0 (3aR,4R,6S,7aR)-4-Benzyloxymethyl-6-methoxy-2,2-dimethyl-dihydro-[1,3]dioxolo[4,5-c]pyran-7-one 
• 71512-68-0 methyl 1,2,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

BORON CLUSTER-COUPLED COMPOUND

To provide a novel boron-containing compound which increases intratumorous accumulation and tumor retention, and is efficiently taken into a tumor cell.SOLUTION: The present invention relates to a compound represented by formula (I) in the figure or a salt thereof. [In the formula, X represents a divalent to pentavalent organic group; Y represents a linker structure; R represents a monovalent group comprising boron clusters; and n represents 2, 3, 4 or 5.SELECTED DRAWING: None

Dual-participation protecting group solves the anomeric stereocontrol problems in glycosylation reactions

The 2,2-dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) group permits, via robust neighboring group participation (NGP) or long distance participation (LDP) effects, the stereocontrolled 1,2-trans, 1,2-cis, as well as β-2,6-dideoxy glycosidic bond generation, while suppressing the undesired orthoester byproduct formation. The robust stereocontrol capability of the DMNPA is due to the dual-participation effect from both the ester functionality and the nitro group, verified by control reactions and DFT calculations and further corroborated by X-ray spectroscopy.

Tin-mediated regioselective benzylation and allylation of polyols: Applicability of a catalytic approach under solvent-free conditions

The first catalytic version of the stannylene-mediated benzylation and allylation of polyols is reported. The methodology is based on a simple solvent-free protocol that significantly advances, in terms of both experimental ease and synthetic scope, the a