82659-57-2

Basic information

• Product Name: 3-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)prop-1-ene
• Synonyms: 3-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)prop-1-ene
• CAS NO: 82659-57-2
• Molecular Weight: 564.722
• Mol File: 82659-57-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)prop-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)prop-1-ene(82659-57-2)
• EPA Substance Registry System: 3-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)prop-1-ene(82659-57-2)

Safety Data

• Hazardous Substances Data: 82659-57-2(Hazardous Substances Data)

Upstream product

• 53008-62-1 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl iodide 
• 2622-05-1 allylmagnesium bromide 
• 3866-62-4 1-O-acetyl-2,3,4,6-tetra-O-benzyl-β-D-galactopyranoside 
• 762-72-1 allyl-trimethyl-silane 
• 53008-63-2 methyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside 
• 82598-84-3 2,3,4,6-tetra-O-benzyl-D-galactonolactone 
• 1730-25-2 allylmagnesium bromide 
• 147242-49-7 (4-Nitro-phenyl)-((2S,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methanone 

Downstream Products

• 96689-97-3 ((2R,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-acetaldehyde 
• 87256-53-9 (S)-5-[(1S,2R,3R)-1,2-Dihydroxy-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyl]-dihydro-furan-2-one 
• 87256-52-8 (Z)-(6R,7R)-6-Hydroxy-7-methyl-8-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-oct-4-enoic acid 
• 83861-86-3 (S)-1-{(4S,5R)-2,2-Dimethyl-5-[(R)-1-methyl-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-[1,3]dioxolan-4-yl}-pent-4-en-1-ol 
• 87263-31-8 (2R,3R)-1-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butan-2-ol 
• 87256-51-7 [(2R,3R)-3-((2S,3R,4S,5S,6S)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-oxiranyl]-methanol 
• 87256-50-6 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol 
• 87256-54-0 (S)-1-((2R,3aR,5R,6R,7S,7aS)-6,7-Bis-benzyloxy-5-benzyloxymethyl-hexahydro-furo[3,2-b]pyran-2-yl)-ethane-1,2-diol 
• 477247-02-2 (3S,5S,6R)-3-(2'-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)ethyl)-4-(t-butoxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 

Relevant articles and documents

Mild cu(Otf)2-mediated C-glycosylation with chelation-assisted picolinate as a leaving group

C-Glycosylation reactions of glycosyl picolinates with allyltrimethylsilane or silyl enol ethers were developed. Picolinate as a chelation-assisted leaving group could be activated by Cu(OTf)2 and avoided the use of harsh Lewis acids. The glycosylations were operated under mild neutral conditions and gave the corresponding C-glycosides in up to 95% yield with moderate to excellent stereoselectivities.

Adaptable synthesis of C-glycosidic multivalent carbohydrates and succinamide-linked derivatization

A modular approach to the synthesis of trivalent C-glycosidic carbohydrates is described. The approach is illustrated employing carboxylate-terminated C-glycosidic d-mannose, d-glucose, and d-galactose derivatives with different length C1-linked spacer un

Highly Stereoselective Approaches to α- and β-C-Glycopyranosides

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