87256-50-6

Basic information

• Product Name: 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol
• Synonyms: 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol
• CAS NO: 87256-50-6
• Molecular Weight: 594.748
• Mol File: 87256-50-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol(87256-50-6)
• EPA Substance Registry System: 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol(87256-50-6)

Safety Data

• Hazardous Substances Data: 87256-50-6(Hazardous Substances Data)

Upstream product

• 198268-99-4 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-enoic ethyl ester 
• 80300-30-7 1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 82659-52-7 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene 
• 120520-77-6 2-{(2R,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl] tetrahydro-2H-pyran-2-yl}acetaldehyde 
• 81972-19-2 α-allyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 96689-97-3 ((2R,3S,4R,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-acetaldehyde 

Downstream Products

• 87256-53-9 (S)-5-[(1S,2R,3R)-1,2-Dihydroxy-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyl]-dihydro-furan-2-one 
• 87256-52-8 (Z)-(6R,7R)-6-Hydroxy-7-methyl-8-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-oct-4-enoic acid 
• 83861-86-3 (S)-1-{(4S,5R)-2,2-Dimethyl-5-[(R)-1-methyl-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-[1,3]dioxolan-4-yl}-pent-4-en-1-ol 
• 87263-31-8 (2R,3R)-1-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butan-2-ol 
• 444150-28-1 2-acetamido-2-[3-benzyloxy-4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)benzyl]malonic diethyl ester 
• 444150-22-5 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-3-benzyloxybenzoic ethyl ester 
• 444150-18-9 7-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-3-ethoxycarbonyl-hepta-3,5-dienoic acid 
• 444150-24-7 1-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-ylmethyl)-2-benzyloxy-4-hydroxymethylbenzene 

Relevant articles and documents

A novel general route for the synthesis of C-glycosyl tyrosine analogues.

A general method for the synthesis of C-glycosyl amino acids is described here. The stereoisomerically pure tyrosine analogues alpha-L-4 and beta-L-6 are prepared in reasonable overall yields from allyl derivatives 10 and 11. The key step is a benzannulation procedure which is employed in the creation of the aromatic ring that bears the amino acid function.