82769-19-5

Basic information

• Product Name: (+/-)-mesembranol
• Synonyms: (+/-)-mesembranol
• CAS NO: 82769-19-5
• Molecular Weight: 291.39
• Mol File: 82769-19-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+/-)-mesembranol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-mesembranol(82769-19-5)
• EPA Substance Registry System: (+/-)-mesembranol(82769-19-5)

Safety Data

• Hazardous Substances Data: 82769-19-5(Hazardous Substances Data)

Upstream product

• 6023-73-0 mesembrine 
• 2987-06-6 4-(benzyloxy)cyclohexanone 
• 125032-05-5 (1R^*,2S^*,4R^*)-4-(benzyloxy)-2-bromo-1-(3,4-dimethoxyphenyl)cyclohexan-1-ol 
• 129920-37-2 (1R^*,2S^*,4R^*)-4-(benzyloxy)-1,2-epoxy-1-(3,4-dimethoxyphenyl)cyclohexane 
• 2859-78-1 4-Bromoveratrole 
• 82732-24-9 (1S,6R)-4-Benzyloxy-8,8-dichloro-1-(3,4-dimethoxy-phenyl)-bicyclo[4.2.0]octan-7-one 
• 82732-18-1 1-methyl-3a-(3,4-dimethoxyphenyl)-6-(benzyloxy)-cis-octahydroindol-2-one 
• 82732-17-0 1-(3,4-dimethoxyphenyl)-4-(benzyloxy)-cis-bicyclo<4.2.0>octan-7-one 
• 92829-83-9 1,4-dioxaspiro<4,5>decan-8-ol benzyl ether 
• 22428-87-1 4,4-ethylenedioxycyclohexan-1-ol 
• 125032-07-7 (1S^*,2R^*,5R^*)-N-<5-(benzyloxy)-2-hydroxy-2-(3,4-dimethoxyphenyl)cyclohex-1-yl>-α,α-dichloro-N-methylacetamide 
• 125032-08-8 (1S^*,5R^*)-N-<5-(benzyloxy)-2-(3,4-dimethoxyphenyl)cyclohex-2-en-1-yl>-α,α-dichloro-N-methylacetamide 
• 82732-18-1 (3aR^*,6R^*,7aS^*)-6-(benzyloxy)octahydro-3a-(3,4-dimethoxyphenyl)-1-methylindol-2-one 
• 125032-06-6 (1R^*,2S^*,4R^*)-4-(benzyloxy)-1-(3,4-dimethoxyphenyl)-2-(methylamino)cyclohexan-1-ol 

Downstream Products

• 82769-20-8 (+/-)-6-epimesembranol 
• 6023-73-0 mesembrine 

Relevant articles and documents

Radical Cyclization of N-(Cyclohex-2-enyl)-α,α-dichloroacetamides. Stereoselective Syntheses of (+/-)-Mesembranol and (+/-)-Elwesine

Stereoselective syntheses of the Sceletium alkaloid (+/-)-mesembranol (2) and the Amaryllidaceae alkaloid (+/-)-elwesine (3) have been achieved.A key step in the syntheses involves the Bu3SnH-mediated radical cyclization of the dichloroacetamides 34 and 4

Synthesis of (+/-)-Mesembranol and (+/-)-O-Methyljoubertiamine. Aza-Ring Expansion of cis-Bicyclooctanones

The Syntheses of (+/-)-mesembranol (1) and (+/-)-O-methyljoubertiamine (2) are described.Each synthesis is developed from a regio- and stereospecific heteroannelation sequence of the respective 1-arylcyclohexanes 4 and 10 to provide the 3a-aryl-cis-octahy