82732-19-2Relevant articles and documents
Radical Cyclization of N-(Cyclohex-2-enyl)-α,α-dichloroacetamides. Stereoselective Syntheses of (+/-)-Mesembranol and (+/-)-Elwesine
Ishibashi, Hiroyuki,So, Taru Su,Okochi, Kyoko,Sato, Tatsunori,Nakamura, Nobuyuki,et al.
, p. 95 - 102 (2007/10/02)
Stereoselective syntheses of the Sceletium alkaloid (+/-)-mesembranol (2) and the Amaryllidaceae alkaloid (+/-)-elwesine (3) have been achieved.A key step in the syntheses involves the Bu3SnH-mediated radical cyclization of the dichloroacetamides 34 and 4
Synthesis of (+/-)-Mesembranol and (+/-)-O-Methyljoubertiamine. Aza-Ring Expansion of cis-Bicyclooctanones
Jeffs, Peter W.,Cortese, Nicholas A.,Wolfram, Joachim
, p. 3881 - 3886 (2007/10/02)
The Syntheses of (+/-)-mesembranol (1) and (+/-)-O-methyljoubertiamine (2) are described.Each synthesis is developed from a regio- and stereospecific heteroannelation sequence of the respective 1-arylcyclohexanes 4 and 10 to provide the 3a-aryl-cis-octahy