828915-85-1Relevant articles and documents
A concise sultone route to highly oxygenated 1,10-seco-eudesmanolides - enantioselective total synthesis of the antileukemic sesquiterpene lactones (-)-eriolanin and (-)-eriolangin
Merten, Joern,Hennig, Andre,Schwab, Pia,Froehlich, Roland,Tokalov, Sergey V.,Gutzeit, Herwig O.,Metz, Peter
, p. 1144 - 1161 (2007/10/03)
Using a sultone as the key intermediate, the first enantioselective total synthesis of the antileukemic 1,10-seco-eudesmanolides (-)-eriolanin (1) and (-)-eriolangin (2) was achieved, which also established the hitherto unknown absolute configuration of t
Enantioselective total synthesis of the highly oxygenated 1,10-seco-eudesmanolides eriolanin and eriolangin
Merten, Joern,Froehlich, Roland,Metz, Peter
, p. 5991 - 5994 (2007/10/03)
Sultones of swing: A sultone served as the key intermediate in the first enantioselective total syntheses of the bioactive title compounds (see scheme), the absolute configuration of which is now established. Starting from 2-bromo-1-(2-furyl)ethanone, 24