834-99-1

Basic information

• Product Name: 1-METHOXYPHENANTHRENE
• Synonyms: 1-METHOXYPHENANTHRENE
• CAS NO: 834-99-1
• Molecular Formula: C15H12O
• Molecular Weight: 208.26
• Mol File: 834-99-1.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 375.5°C at 760 mmHg
• Flash Point: 150.8°C
• Appearance: /
• Density: 1.146g/cm³
• Vapor Pressure: 1.67E-05mmHg at 25°C
• Refractive Index: 1.679
• CAS DataBase Reference: 1-METHOXYPHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHOXYPHENANTHRENE(834-99-1)
• EPA Substance Registry System: 1-METHOXYPHENANTHRENE(834-99-1)

Safety Data

• Hazardous Substances Data: 834-99-1(Hazardous Substances Data)

Usage

Class

Methoxyphenanthrenes

Derived from

Phenanthrene

Addition

Methoxy group

Type

Polycyclic aromatic hydrocarbon (PAH)

Common sources

Coal tar, crude oils

Applications

Organic synthesis, pharmaceuticals and fine chemicals production

Environmental and health concerns

Potential toxicity, carcinogenic effects

InChI:InChI=1/C15H12O/c1-16-15-8-4-7-13-12-6-3-2-5-11(12)9-10-14(13)15/h2-10H,1H3

Upstream product

• 1024598-29-5 3'-methoxy-2-(2''-methoxyvinyl)-1,1'-biphenyl 
• 10365-98-7 3-methoxyphenylboronic acid 
• 130089-19-9 1-bromo-2-(2-methoxyethenyl)benzene 
• 6630-33-7 ortho-bromobenzaldehyde 
• 2433-56-9 1-phenanthrenol 
• 77-78-1 dimethyl sulfate 
• 857825-31-1 8-methoxy-1,2,3,4-tetrahydrophenanthrene 
• 341024-19-9 8-methoxy-phenanthrene-9-carboxylic acid 
• 90585-32-3 1,1-dibromo-2-(2-methoxyphenyl)ethene 
• 135-02-4 ortho-anisaldehyde 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 203176-36-7 1-bromo-2-(o-methoxyphenyl)ethylene 
• 529-28-2 4-iodoanisol 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 

Relevant articles and documents

A novel and efficient synthesis of phenanthrene derivatives via palladium/norbornadiene-catalyzed domino one-pot reaction

Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromoben-zoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleasantly, this protocol has a wider substrate range, shorter reaction times and higher yields of products than previously reported methods.

Regioselective Synthesis of Polycyclic and Heptagon-embedded Aromatic Compounds through a Versatile π-Extension of Aryl Halides

A versatile π-extension reaction was developed based on the three-component cross-coupling of aryl halides, 2-haloarylcarboxylic acids, and norbornadiene. The transformation is driven by the direction and subsequent decarboxylation of the carboxyl group, while norbornadiene serves as an ortho-C?H activator and ethylene synthon via a retro-Diels–Alder reaction. Comprehensive DFT calculations were performed to account for the catalytic intermediates.