83554-67-0

Basic information

• Product Name: CHEMBRDG-BB 9070687
• Synonyms: CHEMBRDG-BB 9070687;N-METHYL-3-PHENYL-2-PROPEN-1-AMINE;N-methyl-3-phenyl-2-propen-1-amine(SALTDATA: FREE)
• CAS NO: 83554-67-0
• Molecular Formula: C₁₀H₁₃N
• Molecular Weight: 147.22
• Mol File: 83554-67-0.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 252.1°C at 760 mmHg
• Flash Point: 123.8°C
• Appearance: /
• Density: 0.945g/cm³
• Vapor Pressure: 0.0197mmHg at 25°C
• Refractive Index: 1.56
• PKA: 10.06±0.10(Predicted)
• CAS DataBase Reference: CHEMBRDG-BB 9070687(CAS DataBase Reference)
• NIST Chemistry Reference: CHEMBRDG-BB 9070687(83554-67-0)
• EPA Substance Registry System: CHEMBRDG-BB 9070687(83554-67-0)

Safety Data

• Statements: 41-52/53
• Safety Statements: 26-39
• WGK Germany: 3
• Hazardous Substances Data: 83554-67-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13N/c1-11-9-5-8-10-6-3-2-4-7-10/h2-8,11H,9H2,1H3/b8-5+

Upstream product

• 4392-24-9 Cinnamyl bromide 
• 74-89-5 methylamine 
• 2757-10-0 (E)-N-methyl-3-phenyl-acrylamide 
• 34477-69-5 <2-(methylamino)ethyl>triphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 140-10-3 (E)-3-phenylacrylic acid 
• 102-92-1 Cinnamoyl chloride 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 72037-46-8 1-methyl-4-phenyl-1-azabutadiene 
• 104-55-2 3-phenyl-propenal 

Downstream Products

• 98977-53-8 (2E)-N-benzyl-N-methyl-3-phenylprop-2-en-1-amine 
• 42817-44-7 (E)-N,N-dimethyl-3-phenylprop-2-en-1-amine 
• 98977-70-9 (E)-N-methyl-N-(3-phenyl-2-propenyl)-4-s-hydrindacenemethanamine 
• 98977-67-4 (E)-N-methyl-N-(3-phenyl-2-propenyl)-3-indenemethanamine 
• 83554-66-9 (E)-N-methyl-N-(3-phenyl-2-propenyl)-2H-1-benzopyran-4-methanamine 
• 98977-68-5 (E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine 
• 55702-58-4 1-methyl-2-phenylazetidine 
• 122333-67-9 2-Benzyl-1-methyl-aziridine 
• 97206-63-8 N-methyl N-cinnamylamino-1 propanethiol-2 
• 109519-67-7 1,3-Dimethyl-6-[methyl-((E)-3-phenyl-allyl)-amino]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 
• 98977-85-6 (E)-N-methyl-N-(3-phenyl-2-propenyl)-1-naphthamide 

Relevant articles and documents

Asymmetric and Geometry-Selective α-Alkenylation of α-Amino Acids

Both E- and Z-N′-alkenyl urea derivatives of imidazolidinones may be formed selectively from enantiopure α-amino acids. Generation of their enolate derivatives in the presence of K+ and [18]crown-6 induces intramolecular migration of the alkeny

Access to functionalized imidazolidin-2-one derivatives by Iron-catalyzed oxyamination of alkenes

Functionalized imidazolidin-2-one were prepared by using an iron-catalyzed alkene oxyamination reaction. Hy-droxylamine derivatives were used in this atom-economical process, and the addition of an external oxidant was not required. The conditions developed were shown to be efficient for mono-, di-, and trisubstituted double bonds, and a large scope of diamino alcohol precursors were delivered in good yields with good diastereoselectivities. The mechanistic pathway was studied and appears to involve both a fused aziridine and a carbocationic species.

Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Allylic Amines

A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylic ammonium ylides via in situ activation of tertiary allylic amines with arynes under mild conditions. Using 2-(trimethylsilyl)aryl triflates as aryne precurso