83686-89-9Relevant academic research and scientific papers
FLASH VACUUM THERMOLYSIS OF β-KETO-TRIMETHYLSILYL-ENOL-ETHERS. SYNTHESIS OF ALLENIC AND FURANIC DERIVATIVES
Jullien, J.,Pechine, J. M.,Perez, F.,Piade, J. J.
, p. 1413 - 1416 (2007/10/02)
Thermolysis at 800 deg C of a series of β-keto-trimethylsilyl-enol-ethers allows the elimination of a trimethylsilanol molecule through a 1,5 rearrangement.The reduction products are furanic derivatives, which are obtained in often good yields through an allenic intermediate, which has been isolated.
