38109-75-0

Basic information

• Product Name: 3-Buten-2-one, 4-phenyl-4-[(trimethylsilyl)oxy]-
• CAS NO: 38109-75-0
• Molecular Formula: C13H18O2Si
• Molecular Weight: 234.37
• Mol File: 38109-75-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-one, 4-phenyl-4-[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-one, 4-phenyl-4-[(trimethylsilyl)oxy]-(38109-75-0)
• EPA Substance Registry System: 3-Buten-2-one, 4-phenyl-4-[(trimethylsilyl)oxy]-(38109-75-0)

Safety Data

• Hazardous Substances Data: 38109-75-0(Hazardous Substances Data)

Upstream product

• 3385-94-2 hexamethyldisilathiane 
• 93-91-4 1-phenylbutan-1,3-dione 
• 7677-24-9 trimethylsilyl cyanide 
• 43112-38-5 3-(trimethylsilyl)-2-oxazolidinone 
• 75-77-4 chloro-trimethyl-silane 
• 74590-81-1 1-(trimethylsiloxy)-1-phenyl-1-buten-3-one 
• 83686-89-9 4-phenyl-(trimethylsilyloxy)-2(E)-buten-2-one 
• 83686-98-0 4-phenyl-(trimethylsilyloxy)-2(Z)-buten-2-one 
• 38109-69-2 N,O-bis(trimethylsilane)acetamide 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 83686-98-0 4-phenyl-(trimethylsilyloxy)-2(Z)-buten-2-one 
• 83686-89-9 4-phenyl-(trimethylsilyloxy)-2(E)-buten-2-one 
• 74590-81-1 1-(trimethylsiloxy)-1-phenyl-1-buten-3-one 
• 1190219-93-2 methyl 2-phenyl-4,5-dimethyl-6-(phenylsulfanyl)-benzoate 
• 1141849-77-5 (3-hydroxy-5-methylbiphenyl-2-yl)(2-methoxyphenyl)methanone 
• 109801-25-4 2-fluoro-1-phenyl-1,3-butanedione 

Relevant articles and documents

REACTIONS OF CYANOTRIMETHYLSILANE WITH β-DIKETONES

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Silylation of 1,3-Dicarbonyl Compounds with 2-Oxo-3-trimethylsilyltetrahydro-1,3-oxazole

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A Novel Cycloaromatization Reaction. Regiocontrolled Synthesis of Substituted Methyl Salicylates

A new method of constructing six-membered rings, involving the condensation of two three-carbon units, one with two nucleophilic sites and the other containing two electrophilic sites, is reported.The regiochemistry of the reaction is controlled by the differential reactivities of these sites. 1,3-Bis(trimethylsiloxy)-1-methoxybuta-1,3-diene (1) constitutes the three-carbon fragment with two nucleophilic sites.Condensation of 1 with various equivalents of β-dicarbonyl compounds and titanium tetrachloride gave substituted methyl salicylates.The regiochemistry is controlled by the order of reactivity of the electrophilic sites, which is conjugate position of enone > ketone > monothioacetal, acetal.