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5-Hexen-1-ol, 2-(phenylmethoxy)-, (2R)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 83861-87-4 Structure
  • Basic information

    1. Product Name: 5-Hexen-1-ol, 2-(phenylmethoxy)-, (2R)-
    2. Synonyms:
    3. CAS NO:83861-87-4
    4. Molecular Formula: C13H18O2
    5. Molecular Weight: 206.285
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 83861-87-4.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 5-Hexen-1-ol, 2-(phenylmethoxy)-, (2R)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 5-Hexen-1-ol, 2-(phenylmethoxy)-, (2R)-(83861-87-4)
    11. EPA Substance Registry System: 5-Hexen-1-ol, 2-(phenylmethoxy)-, (2R)-(83861-87-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 83861-87-4(Hazardous Substances Data)

83861-87-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 83861-87-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,8,6 and 1 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 83861-87:
(7*8)+(6*3)+(5*8)+(4*6)+(3*1)+(2*8)+(1*7)=164
164 % 10 = 4
So 83861-87-4 is a valid CAS Registry Number.

83861-87-4Relevant articles and documents

Synthesis of Decytospolide A, B and Their C-3 Epimers Using Stereoselective Oxypalladation

Kurogome, Yuji,Hattori, Yasunao,Makabe, Hidefumi

, p. 765 - 771 (2016/02/27)

Stereoselective synthesis of decytospolide A and B and their C-3 epimers, which have a 2,6-cis-tetrahydropyran ring, has been achieved in high stereoselectivity and yield. The oxypalladation of single diastereomers of 6-(benzyloxy)-7-hydroxydodec-2-enyl 2

Titanium(IV)-promoted regioselective nucleophilic ring-opening reaction of chiral epoxyallyl alcohols with acids as a tool for ready access to chiral 1,2,3-triol monoesters: Application to stereoselective total synthesis of macrolides

Radha Krishna, Palakodety,Ramana, D. Venkata

experimental part, p. 674 - 679 (2012/03/22)

Titanium(IV)-promoted regioselective ring-opening reaction of chiral epoxy-allyl alcohols (Sharpless conditions as the key strategic step) is developed as a tool for ready access to chiral 5,6-dihydroxyoct-7-en-4-yl alkoxylates. Later, the synthetic utility of products thereof was demonstrated through the RCM based stereoselective synthesis of various natural products.

Enantioselective synthesis of α-benzyloxy-ω-alkenals: application to the synthesis of (+)-exo-brevicomin, (+)-iso-exo-brevicomin, and (-)-isolaurepan

Prasad, Kavirayani R.,Anbarasan, Pazhamalai

, p. 1419 - 1427 (2008/02/11)

The enantioselective synthesis of α-benzyloxy aldehydes containing a terminal alkene was carried out from chiral pool l-(+)-tartaric acid by employing the stereoselective reduction of a 1,4-diketone as the key step. The synthetic utility of these aldehyde

Asymmetric synthesis of unsaturated α-benzyloxyaldehydes: An enantioselective synthesis of (+)-exo-brevicomin

Prasad, Kavirayani R.,Anbarasan, Pazhamalai

, p. 3951 - 3953 (2007/10/03)

Enantioselective synthesis of α-hydroxy aldehydes with an alkene tether was accomplished from l-(+)-tartaric acid, employing stereoselective reduction of a 1,4-diketone with L-selectride as the key step. Synthetic utility of these aldehydes was demonstrat

A new access to enantiopure β-hydroxylated piperidines from N-Boc-2- acyloxazolidines. Application to the synthesis of (-)-desoxoprosopinine and (+)-pseudoconhydrine

Agami, Claude,Couty, Francois,Lam, Hubert,Mathieu, Helene

, p. 8783 - 8796 (2007/10/03)

The synthesis of (-)-desoxoprosopinine and (+)-pseudoconhydrine were achieved from a common oxazolidine precursor. The three stereocenters present in (-)-desoxoprosopinine as well as the two stereocenters of (+)- pseudoconhydrine were created in highly stereoselective ways. The stereoselectivity observed during the reduction of the ketone moiety in the starting oxazolidine was dependent on the occurrence of a chelated intermediate. The others stereocenters arose from stereoselective reductions or alkylations of intermediate iminium ions.

Stereoselective Synthesis of Aliphatic 1,5,9,13-Polyols using (δ-Alkoxyallyl)stannanes

McNeill, Alan H.,Thomas, Eric J.

, p. 1669 - 1672 (2007/10/02)

Treatment of aliphatic aldehydes with the allyltin trichloride generated from the 4-benzyloxyocta-2,7-dienylstannane 18 and tin(IV)chloride provides stereoselective access to polyhydroxylated compounds with the hydroxyl groups at positions 1,5,9,13- etc.

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