840-59-5Relevant academic research and scientific papers
Ru(II)-arene complexes with N-substituted 3,4-dihydroquinazoline ligands and catalytic activity for transfer hydrogenation reaction
Mercan, Deniz,?etinkaya, Engin,?ahin, Ertan
supporting information, p. 74 - 81 (2013/07/19)
In this study, N-coordinated 3,4-dihydroquinazoline ruthenium(II) complexes were synthesized by the cleavage reaction of [RuCl2(p-cymene)] 2 with N-substituted 3,4-dihydroquinazolines. In addition, the X-ray crystal structure of 2,4,6-trimethylbenzyl substituted 3,4-dihydroquinazoline Ru(II) complex (1a) is reported. Furthermore, the resulting piano-stool complexes were evaluated as transfer hydrogenation catalysts for reduction of acetophenone in the presence of 2-propanol and KOH at 82°C. All the complexes showed good to excellent performance after 1 h in the conversion of acetophenone to alcohol and the reaction rate was found to be sensitive to changes on the N-substituent. Additionally, the most active catalyst 1a was used in transfer hydrogenation of different ketones to investigate the effect of substituents on ketones.
Two isolated intermediates of the Tr?ger's base: synthesis and mechanism
Wan, Yu,Yuan, Rui,Zhang, Wei-chao,Shi, Yan-hui,Lin, Wei,Yin, Wei,Bo, Rong-cheng,Shi, Jing-jing,Wu, Hui
experimental part, p. 3405 - 3409 (2010/06/21)
By controlling the amount of catalyst 1-methyl-3-(2-(sulfooxy)ethyl)-1H-imidazol-3-ium chloride, two new intermediates of Tr?ger's bases (11, 1,6-dimethyl-3-(4-methylphenyl)-1,4-dihydroquinazolin-3-ium tetrafluoroborate and 12, 8-methyl-2,5-bis-(4-methylp
A novel isocyanate reaction - The formation and structure of unexpected cycloadducts
Tietz, Helmuth,Rademacher, Otto,Zahn, Gernot
, p. 2105 - 2112 (2007/10/03)
Phenyl isocyanate reacts with six-membered cyclic formamidines, e.g. with substituted 3,4-dihydroquinazolines 1, at ambient temperature in an expected route to give the 1,3,5-triazines 4 by [2+2+2] cycloaddition. However, at elevated temperatures the unex
