84039-96-3Relevant academic research and scientific papers
Photo-oxidation of Oxazolidones and Hydantoins in the Presence of Benzophenone
Gramain, Jean-Claude,Remuson, Roland
, p. 2341 - 2346 (2007/10/02)
Irradiation in the presence of benzophenone and oxygen of nitrogen-containing heterocycles having an NCO group yields products arising out of regioselective oxidation α to the nitrogen atom.Direct irradiation (in the absence of benzophenone and oxygen) of 5-methyl- and 5,5-dimethyl-hydantoins yields allophanates.The first step of this reaction involves the homolysis of the C(4) - C(5) bond of the hydantoin.
