84325-97-3Relevant articles and documents
Oxidative Rearrangement of Alkynes to Carboxylic Acid Esters by benzene in Methanol
Moriarty, Robert M.,Vaid, Radhe K.,Duncan, Michael P.,Vaid, Beena K.
, p. 2845 - 2848 (1987)
A direct synthesis of methyl aryl alkanoate via oxidative rearrangement of alkynes using benzene in methanol is described.
Ni-catalyzed activation of α-chloroesters: a simple method for the synthesis of α-arylesters and β-hydroxyesters
Durandetti, Muriel,Gosmini, Corinne,Périchon, Jacques
, p. 1146 - 1153 (2007/10/03)
Coupling reactions of α-chloroesters with aryl halides (α-arylation) or carbonyl compounds (Reformatsky) using nickel catalyst allow, under mild conditions, the preparation of various functionalized aryl propionic acid derivatives or β-hydroxyesters. In the synthesis of aryl propionic acid derivatives, the process is efficient with aryl halides bearing either electron-withdrawing or electron-donating groups.