84547-45-5Relevant academic research and scientific papers
Kinetic resolution of β- and γ-hydroxy sulfides by fungal lipase from Humicola lanuginosa
Singh, Satwinder,Kumar, Subodh,Chimni, Swapandeep Singh
, p. 231 - 240 (2007/10/03)
Racemic β- and γ-hydroxy sulfides were resolved by Humicola lanuginosa lipase catalyzed transesterification using vinyl acetate both as acyl donor and solvent. The effect of substituents and spacer length on rate of reaction and enantioselectivity is obse
A NEW SYNTHESIS OF α,β-UNSATURATED γ- AND δ-LACTONS VIA INTRAMOLECULAR ACYLATION OF α-SULFINYL CARBANION
Pohmakotr, Manat,Jarupan, Prapanpong
, p. 2253 - 2256 (2007/10/02)
A new synthesis of α,β-unsaturated γ- and δ-lactones involving the intramolecular acylation of α-sulfinyl carbanion followed by pyrolisis is described.
A New and Convenient Synthetic Method for Cyclopropyl Phenyl Sulfides
Tanaka, Kazuhiko,Uneme, Hideki,Matsui, Shuichi,Kaji, Aritsune
, p. 2965 - 2972 (2007/10/02)
The reactions of a variety of 1,3-bis(phenylthio)propanes with butyllithium have been shown to produce cyclopropyl phenyl sulfides in good to high yields.A new and convenient in situ preparation of 1-lithiocyclopropyl phenyl sulfide can be readily carried out by treating 1,3-bis(phenylthio)propane with 2 equiv. of butyllithium at 0 degC in THF.The reaction with electrophiles proceeds in good yield.O-Aryl and O-alkyl S-cyclopropyl dithiocarbonates also can be prepared in good yields. 1,2-Bis(phenylthio)ethane was converted to phenyl vinyl sulfide on treatment with butyllithium, while 1,4-bis(phenylthio)butane was recovered unchanged by a similar treatment.
