85135-67-7Relevant academic research and scientific papers
MESOMORPHOGENS. VI. CHOLESTERYL AND THIOCHOLESTERYL ESTERS OF CYCLOALKANECARBOXYLIC ACIDS
Bogatskii, A. V.,Kondrat'eva, R. V.,Galatina, A. I.,Novikova, N. S.
, p. 1286 - 1290 (2007/10/02)
The acylation of cholesterol and thiocholesterol by acid chlorides of ω-cycloalkane carboxylic acid gave the cholesteryl and thiocholesteryl esters of the corresponding acids.The mesogenic capacity of the ω-cycloalkanoates of cholesterol and thiocholesterol is largely a factor of the polarizability of these molecules and not their spatial configuration.A decrease in the geometric anisotropy and concurrent increase in polarizability impart instability to the meso phase of most ω-cycloalkanoates.
