853193-64-3Relevant articles and documents
Remote asymmetric induction in an intramolecular ionic Diels-Alder reaction: Application to the total synthesis of (+)-dihydrocompactin
Sammakia, Tarek,Johns, Deidre M.,Kim, Ganghyeok,Berliner, Martin A.
, p. 6504 - 6505 (2007/10/03)
The total synthesis of (+)-dihydrocompactin via an intramolecular ionic Diels-Alder reaction that proceeds with remote stereocontrol is described. This reaction proceeds by an intermediate vinyl-oxocarbenium ion (6), the conformational constraints of whic