853304-33-3Relevant academic research and scientific papers
Water-Tolerant ortho-Acylation of Phenols
Dong, Shuang-Feng,Gao, Zhi-Yuan,He, Yu,Liu, Xu,Loh, Teck-Peng,Tian, Jie-Sheng,Wu, Peng
supporting information, p. 6594 - 6598 (2021/09/02)
A metal-free, water-tolerant, and one-pot process for ortho-acylation of phenols promoted by the iodine source/hydrogen peroxide system has been developed. This transformation undergoes ether formation, iodocyclization, C-C bond cleavage, and oxidative hydrolysis in a one-step manner, which is supported by control experiments.
Direct Preparation of 3-Iodochromenes from 3-Aryl- and 3-Alkyl-2-propyn-1-ols with Diaryliodonium Salts and NIS
Sasaki, Teppei,Miyagi, Kotaro,Moriyama, Katsuhiko,Togo, Hideo
supporting information, p. 944 - 947 (2016/03/15)
On the basis of a study of the O-phenylation of 3-phenyl-2-propyn-1-ol with diphenyliodonium triflate and t-BuONa, a variety of 4-aryl-3-iodo-2H-benzopyrans were prepared in good to moderate yields in one pot from the reaction of 3-aryl-2-propyn-1-ols wit
Synthesis of 3,4-disubstituted 2H-benzopyrans through C-C bond formation via electrophilic cyclization
Worlikar, Shilpa A.,Kesharwani, Tanay,Yao, Tuanli,Larock, Richard C.
, p. 1347 - 1353 (2007/10/03)
(Chemical Equation Presented) The electrophilic cyclization of substituted propargylic aryl ethers by I2, ICl, and PhSeBr produces 3,4-disubstituted 2H-benzopyrans in excellent yields. This methodology results in vinylic halides or selenides un
Intramolecular iodoarylation reaction of alkynes: Easy access to derivatives of benzofused heterocycles
Barluenga, Jose,Trincado, Monica,Marco-Arias, Maria,Ballesteros, Alfredo,Rubio, Eduardo,Gonzalez, Jose M.
, p. 2008 - 2010 (2007/10/03)
The iodoarylation reaction of heteroatom-tethered ω-aryl-alkynes offers an efficient and straightforward entry to heterocycles. As a result, both C-C ring-closing from readily available precursors, and concomitant selective iodination take place. The firs
