854-42-2Relevant academic research and scientific papers
Copper/Nickel-Catalyzed Selective C–S/S–S Bond Formation Starting from O-Alkyl Phenylcarbamothioates
Dong, Zhi-Bing,Gao, Ming-Yuan,Guo, Jia,Peng, Kang,Yi, Yu-Yan
, (2020/03/16)
A convenient and effective method is described to construct C–S/S–S bond starting from O-alkyl phenylcarbamothioates, giving diverse O-alkyl S-phenyl phenylcarbonimidothioates and isothiourea disulfides, respectively. The C–S bond formation products (O-al
Acid-catalysed Rearrangement of Bis-5,6-Dihydro-4H-1,3-thiazin-2-yl and Other Disulphides and Related Reactions
Barrett, Anthony G. M.,Barton, Derek H. R.,Colle, Roberto
, p. 665 - 671 (2007/10/02)
Some dithiocarbamates, thiocarbamates, and thiourea derivatives have been oxidised to the disulphides 1X(R2N=)C>2S2 with iodine.In the presence of trifluoroacetic acid, these lost sulphur giving the thiocarbonyl derivatives R1X(R2N=)C-N(R2)CSR1 (R1, R2, X =3, S; 2, S; Me, Me, S; Et, PhCH2, O; 5α-cholestan-3β-yl, Et, O; and Me, Ph, NMe).These rearrangements were most plausibly intramolecular, but proceeded by varying extents of intermolecular scrambling.
