85429-30-7

Basic information

• Product Name: ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine
• Synonyms: ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine
• CAS NO: 85429-30-7
• Molecular Weight: 226.116
• Mol File: 85429-30-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine(85429-30-7)
• EPA Substance Registry System: ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine(85429-30-7)

Safety Data

• Hazardous Substances Data: 85429-30-7(Hazardous Substances Data)

Upstream product

• 14548-16-4 Dimethyl-(1-phenyl-vinyl)-amine 

Downstream Products

• 93-55-0 1-phenyl-propan-1-one 
• 85429-54-5 Dimethyl-((E)-1-phenyl-but-1-enyl)-amine 
• 85429-55-6 1-Phenyl-1-dimethylamino-1-hexen 
• 39167-60-7 Dimethyl-((E)-1-phenyl-propenyl)-amine 
• 942-92-7 caprophenone 
• 109-65-9 1-bromo-butane 
• 85429-36-3 C₁₀H₁₂LiN 

Relevant articles and documents

Enamines β-lithiees. I. Preparations et reactions d'alkylation

The action of alkyllithium reagents on β-bromoenamines 1-9 quickly yields, in THF, β-lithioenamines through halogen - metal exchange.If metallic lithium is used instead of organolithium compounds, β-lithioenamines are also formed but in this case they are accompanied by small amounts of by-products.The action of alkyllithium reagents R1Li on the β-chloroenamine 10 provides a new source of β-lithioenamines in which nucleophilic insertion of the R1 group takes place. β-Lithioenamines are stable compounds even up to 20 deg C in most cases.With alkyl iodides, β-lithioenamines react vigorously even at low temperature.The reaction is stereospecific with retention of configuration.This reaction generates either β-substituted enamines or, by easy acidic hydrolysis, α-substituted carbonyl compounds.The C-alkylation reaction is observed alone.