14548-16-4

Basic information

• Product Name: Benzenemethanamine, N,N-dimethyl-a-methylene-
• Synonyms: dimethylamino-2 styrene;N.N-Dimethyl-N-(1-phenylvinyl)amine;N,N-dimethyl-1-phenylethenamine
• CAS NO: 14548-16-4
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Mol File: 14548-16-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N,N-dimethyl-a-methylene-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N,N-dimethyl-a-methylene-(14548-16-4)
• EPA Substance Registry System: Benzenemethanamine, N,N-dimethyl-a-methylene-(14548-16-4)

Safety Data

• Hazardous Substances Data: 14548-16-4(Hazardous Substances Data)

Upstream product

• 124-40-3 dimethyl amine 
• 98-86-2 acetophenone 
• 827-36-1 2-(N,N-dimethylamino)-2-phenylacetonitrile 
• 59983-62-9 Li{(CH₂)(CH₂)P(C₆H₅)2} 
• 611-74-5 N,N-dimethylbenzamide 
• 69097-27-4 2-(dimethylamino)-2-phenylpropanenitrile 
• 21326-49-8 complex of sulfur dioxide with dimethylamine 
• 866-37-5 triethylgermyl dimethylamine 

Downstream Products

• 85429-54-5 1-Phenyl-1-dimethylamino-1-buten 
• 85422-87-3 1-phenyl-2-((2R,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)ethan-1-one 
• 93-55-0 1-phenyl-propan-1-one 
• 85429-54-5 Dimethyl-((E)-1-phenyl-but-1-enyl)-amine 
• 85429-55-6 1-Phenyl-1-dimethylamino-1-hexen 
• 39167-60-7 Dimethyl-((E)-1-phenyl-propenyl)-amine 
• 942-92-7 caprophenone 
• 86358-62-5 C₁₆H₂₀N₄O₉ 
• 81977-59-5 N,N-Dimethyl-2-oxo-2,N'-diphenyl-acetamidine 
• 98-86-2 acetophenone 
• 495-48-7 azoxybenzene 
• 62-53-3 aniline 
• 611-74-5 N,N-dimethylbenzamide 
• 103-70-8 Formanilid 

Relevant articles and documents

ZUR UMSETZUNG VON ARYLMETHYLKETONEN MIT SCHWEFEL, SEKUNDAEREN AMINEN UND SCHWEFELDIOXID

The acetophenones 2 react with different sulfurdioxide-secondary amine adducts 1 and sulfur to yield the red-coloured zwitterionic 2-imino-dithioacetates 3.Enamines can be proved to be intermediates in this reaction.Thus enamines 5 and other derivatives such as acetophenone anil, acetophenone diethyl acetal and diphenacyl sulfide also give 3.In the absence of 1, 3a react with hydrogen sulfide to form the thioamide of phenylacetic acid 8. Key words: 2-Iminio-dithioacetates; iminium salts; zwitterionic; SO2-secondary amin adducts; Willgerodt-Kindler-reaction; enamines; heptathiocanes.

SYNTHESIS OF α-DIALKYLAMINOSTYRENES AND THEIR REACTION WITH AZODICARBOXYLIC ESTER AND COMPOUNDS CONTAINING AN ACTIVATED MULTIPLE BOND

Lower α-dialkylaminostyrenes react with compounds containing an activated double bond by a mechanism of "vinyl" substitution with the formation of both disubstituted and monosubstituted compounds.The ester groups of the mono- and bisN,N'-di(methoxycarbon