85505-15-3

Basic information

• Product Name: methyl 6-deoxy-β-L-altropyranoside
• CAS NO: 85505-15-3
• Molecular Weight: 178.185
• Mol File: 85505-15-3.mol
• Article Data: 52

Chemical Properties

• CAS DataBase Reference: methyl 6-deoxy-β-L-altropyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-deoxy-β-L-altropyranoside(85505-15-3)
• EPA Substance Registry System: methyl 6-deoxy-β-L-altropyranoside(85505-15-3)

Safety Data

• Hazardous Substances Data: 85505-15-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1226-39-7 p-nitrophenyl-β-D-fucopyranoside 
• 112968-15-7 methyl 2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glalactopyranoside 
• 71117-36-7 methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside 
• 116013-30-0 Benzoic acid (2S,3R,4S,5R,6R)-4,5-diacetoxy-2-bromomethyl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 96048-23-6 methyl-2-O-α-L-rhamnopyranosyl-β-D-fucopyranoside 
• 150650-49-0 methyl 2,3-di-O-acetyl-4-O-benzoyl-6-deoxy-β-D-galactopyranoside 
• 73-34-7 D-Fucose 
• 53942-13-5 Methyl 2,3,4-Tri-O-acetyl-6-deoxy-β-D-galactopyranoside 
• 111476-43-8 methyl β-D-glucopyranoside 6-phenylthionocarbonate 
• 122204-71-1 methyl 2,3,4-tri-O-acetyl-6-bromo-6-deoxy-β-D-glucopyranoside 
• 709-50-2 methyl beta-D-glucopyranoside 
• 7404-26-4 methyl 6-bromo-6-deoxy-β-D-glucopyranoside 
• 6340-57-4 methyl 2,3,4-tri-O-acetyl-6-deoxy-β-D-glucopyranoside 

Downstream Products

• 14064-39-2 L-galacto-2,4,5-Trihydroxy-3-methoxy-hexanal 
• 1379777-16-8 methyl 3-O-phenoxythiocarbonyl-β-L-fucopyranoside 
• 1128-40-1 methyl 6-deoxy-β-L-glucopyranoside 
• 3615-37-0 D-Fucose 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 
• 13322-79-7 methyl 2,6-dideoxy-α-D-lyxo-hexopyranoside 
• 4833-12-9 methyl 4-O-acetyl-3-O-benzyl-2,6-dideoxy-α-D-lyxo-hexopyranoside 
• 3868-01-7 methyl 2,6-dideoxy-3-O-benzyl-4-O-methyl-α-D-lyxo-hexopyranoside 
• 107908-97-4 methyl 2,6-dideoxy-3-O-benzyl-α-D-lyxo-hexopyranoside 
• 15830-76-9 methyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-talopyranoside 
• 4860-85-9 methyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 75336-82-2 Methyl 3-O-benzyl-α-L-rhamnopyranoside 
• 139760-12-6 C₆₁H₆₀O₂₃ 
• 139760-15-9 Methyl O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->3)-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1->2)-3-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside 

Relevant articles and documents

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Synthesis of β-(1→2)-Linked 6-Deoxy- l -altropyranose Oligosaccharides via Gold(I)-Catalyzed Glycosylation of an ortho-Hexynylbenzoate Donor

The β-(1→2)-linked 6-deoxy-l-altropyranose di- to pentasaccharides 2-5, relevant to the O-antigen of the infectious Yersinia enterocolitica O:3, were synthesized for the first time. The challenging 1,2-cis-altropyranosyl linkage was assembled effectively via glycosylation with 2-O-benzyl-3,4-di-O-benzoyl-6-deoxy-l-altropyranosyl ortho-hexynylbenzoate (7) under the catalysis of PPh3AuNTf2. NMR and molecular modeling studies showed that the pentasaccharide (5) adopted a left-handed helical conformation.

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