85686-14-2

Upstream product

• 124-38-9 carbon dioxide 
• 70398-84-4 1,2-Bisbenzene 
• 17534-15-5 Benzene-1,2-dithiol 
• 75-26-3 isopropyl bromide 
• 547765-68-4 2,3-bis-isopropylsulfanyl-benzoic acid methyl ester 
• 178626-86-3 2,3-dimercaptobenzoic acid methyl ester 
• 95-50-1 1,2-dichloro-benzene 

Downstream Products

• 174577-71-0 N-Benzyl-2,3-dimercapto-benzamide 
• 174577-70-9 N-Benzyl-2,3-bis-isopropylsulfanyl-benzamide 
• 174577-75-4 C₆H₃(CH₂NHCOC₆H₃(SH)2)3 
• 1417038-13-1 N-{2,3-bis(isopropylthio)phenyl}carbamoyl azide 
• 1417038-14-2 2,3-bis(isopropylthio)aniline 
• 1417038-15-3 N-{2,3-bis(isopropylthio)phenyl}acetamide 
• 1417038-16-4 N-{2,3-bis(isopropylthio)phenyl}pivalamide 
• 1417038-17-5 N-{2,3-bis(isopropylthio)phenyl}trifluoroacetamide 
• 1417038-18-6 N-{2,3-bis(isopropylthio)phenyl}-2,2,2-triphenylacetamide 
• 1417038-19-7 N-{2,3-bis(isopropylthio)phenyl}-2,2,2-tris(4-tertbutylphenyl)acetamide 
• 1439141-47-5 N-phenyl-2,3-bis(isopropylthio)benzamide 
• 1245720-74-4 C₂₆H₃₀N₂OS₂ 
• 1219836-24-4 N-[2,3-bis(mercapto)benzamido]bis(4-aminophenyl) methane 
• 433288-17-6 1,2-bis[2,3-bis(isopropylsulfanyl)benzamido]ethane 

Relevant academic research and scientific papers

Negatively charged metal-organic hosts with cobalt dithiolene species: Improving PET processes for light-driven proton reduction through host-guest electrostatic interactions

By incorporating 1,2-benzenedithiol as a chelator to construct cobalt dithiolene species, two negatively charged redox-active metal-organic hosts were obtained. By taking advantage of electrostatic interactions, cationic Ru-based photosensitizers were con

A dinuclear iron complex with two cofacial [FeS4] cores linked by covalent ligand periphery clamps and dissociable thiolate bridges

As part of a long-term study of dinuclear iron complexes with sulfur-rich coordination spheres and cofacial, sterically variable binding sites for molecules relevant to nitrogenase, the complex (AsPh4)2 [{Fe('apS4')}2] (5) was synthesized and completely characterized ['apS4'4- = 1,3-bis(2,3-dimercaptobenzamido)propane(4-)]. Complex 5 contains two cofacial [FeIII(S2C6H4R) 2]- units linked by [Fe-S-Fe] thiolate bridges and two peripheral propanediamide ligand backbones that are located on opposite sides of the molecular anion and prevent the complete separation of the two [FeS4] cores of 5 if the Fe-S-Fe bridges dissociate. No marked differences were found in the molecular parameters, spectroscopic, magnetic and electrochemical properties of the [Fe2S8] cores in the anion of 5 and the parent complex [{Fe(S2C6H4)2}2-. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

ortho-lithiation of benzene-1,2-dithiol: A methodology for ortho-functionalization of benzene-1,2-dithiol

The ortho-lithiation of benzene-1,2-dithiol with three equivalents of nBuLi afforded monoas well as di-C-lithiated intermediates. The surprising kinetically controlled formation of di-C-lithiated species offers the opportunity to obtain dimercaptobenzoic and -terephthalic acid derivatives in a onepot synthesis in reasonable yields. Both compounds are versatile building blocks for the synthesis of macrocycles containing arylenedithiol units. Focusing on novel terephthalic acid derivatives, two preparation routes, via amide and via alkyl linkage, respectively, have been elaborated. The reaction sequence (i) sulfur protection using either isopropyl or benzyl groups, (ii) transformation of the carboxylic function into an amide or an alkyl group and (iii) subsequent removal of the protection groups afforded the terephthaldiamidedithiol 6 and the 1,2-bis(2,3-dimercaptophenyl)ethane 11.

Dinuclear complexes with bis (benzenedithiolate) ligands

As a part of a broader study directed towards helical coordination compounds with benzenedithiolate donors, we have synthesized the bis(benzenedithiol) ligands 1,2-bis(2,3-dimercaptobenzamido)ethane (H4-1) and 1,2-bis(2,3-dimercaptophenyl)ethan

Synthese und Koordinationschemie von ortho-funktionalisiertem Dimercaptobenzol: Bausteine fuer tripodale Hexathiol-Liganden

Keywords: Chelatliganden; Molybdaenverbindungen; Thiole; Tripodliganden

STERIC EFFECTS IN THE METALLATION OF ALKOXY- AND DIALKOXY-BENZENES

With the aim of examining the role of steric factors in determining the position of metallation, the reaction of n-butyllithium with a series of 1,2-dialkoxy-, 1,2-alkylthio-, 1,4-dialkoxy-, and 2-t-butyl-1-alkoxy-benzenes has been studied in the presence and in the absence of N,N,N',N'-tetramethylethylenediamine (TMEDA).Steric factors are particularly relevant in the case of 2-t-butyl-alkoxybenzenes where the yields of metallation dramatically decrease passing from the methoxy to the isopropoxy derivative, while with the t-butoxy derivative only cleavage of the ether bond occurs.