85877-79-8Relevant academic research and scientific papers
PERFLUORO-ALKYL MODIFIED ORGANIC SILANE
-
Paragraph 0103; 0104, (2017/05/27)
The present invention relates to a method for preparing perfluoroalkyl modified organic silane, and the method for preparing perfluoroalkyl modified organic silane comprises a step for adding a pyrolytic radical initiator and a tin-based organic metal compound to a mixture of a perfluoroalkyl iodide compound and an organic silane having a double bond. The method for preparing perfluoroalkyl modified organic silane suppresses an additive reaction of the pyrolytic radical initiator and smoothens the reduction of iodine, thereby forming perfluoroalkylalkoxy silane at high efficiency and high purity, causes no chlorine gas, which is a toxic gas, thereby making less environmental loading, such as gas purification facilities, and does not use an expensive metal catalyst and hydrogen gas, thereby preparing perfluoroalkyl modified organic silane easily and economically.COPYRIGHT KIPO 2016
Syntheses and Reactions of Metal Organics. XVIII. Syntheses of (1H,1H,2H,2H-Polyfluoroalkyl)trimethoxysilanes and Surface Modification of Glass Plate
Yoshino, Norio,Yamamoto, Yasushi,Hamano, Katsumi,Kawase, Tokuzo
, p. 1754 - 1758 (2007/10/02)
Four silane coupling agents, (1H,1H,2H,2H-polyfluoroalkyl)trimethoxysilanes ((1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane, C10F21C2H4Si(OCH3)3, (1H,1H,2H,2H-heptadecafluorodecyl)trimethoxysilane, C58F17C2H4Si(OCH3)3, (1H,1H,2H,2H-tridecafluorooctyl)trimethoxysilane, C6F13C2H4Si(OCH3)3, and (1H,1H,2H,2H-nonafluorohexyl)trimethoxysilane, C4F9C2H4Si(OCH3)3), were prepared by the hydrosilylation of trichlorosilane with the corresponding 1H,1H,2H,-polyfluoro-1-alkene in the presence of hydrogen hexachloroplatinate-(IV), followed by reaction with sodium methoxide.The surface modification of glass plate was attempted using these products.From measurements of the contact angles θ (deg) of water and oleic acid against a modified glass plate surface, the coupling agents were found to have high modification ability.The modification produced a glass surface with high oxidation resistance.
